A mechano-responsive supramolecular metal-organic framework (supraMOF) gel material rich in ZIF-8 nanoplates

被引：29
作者：
Chaudhari, Abhijeet K. [1 ]
Tan, Jin-Chong [1 ]
机构：
[1] Univ Oxford, Dept Engn Sci, Multifunct Mat & Composites MMC Lab, Parks Rd, Oxford OX1 3PJ, England
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 61期
基金：
英国工程与自然科学研究理事会;
关键词：
COORDINATION POLYMERS; CHEMICAL SENSORS; DESIGN; RECOGNITION; METALLOGELS; CHEMISTRY; TEMPLATE; REMOVAL; BINDING;
D O I：
10.1039/c7cc03478d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report an unconventional ZIF-8 based supramolecular MOF (supraMOF) material, which is straightforwardly synthesised by leveraging the high concentration reaction (HCR) approach. Akin to traditional low-molecular-weight gels (LMWG), we show that mechano-stimulus responsive behaviour can be achieved through a reversible and fast sol-gel conversion mechanism. Remarkably, the supraMOF gel consists of 2D nanoplates of ZIF-8 with a reduced crystal symmetry.
引用
收藏
页码：8502 / 8505
页数：4
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