A mechano-responsive supramolecular metal-organic framework (supraMOF) gel material rich in ZIF-8 nanoplates

被引：29

作者：

Chaudhari, Abhijeet K. ^{[1
]}

Tan, Jin-Chong ^{[1
]}

机构：

[1] Univ Oxford, Dept Engn Sci, Multifunct Mat & Composites MMC Lab, Parks Rd, Oxford OX1 3PJ, England

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 61期

基金：

英国工程与自然科学研究理事会;

关键词：

COORDINATION POLYMERS; CHEMICAL SENSORS; DESIGN; RECOGNITION; METALLOGELS; CHEMISTRY; TEMPLATE; REMOVAL; BINDING;

D O I：

10.1039/c7cc03478d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report an unconventional ZIF-8 based supramolecular MOF (supraMOF) material, which is straightforwardly synthesised by leveraging the high concentration reaction (HCR) approach. Akin to traditional low-molecular-weight gels (LMWG), we show that mechano-stimulus responsive behaviour can be achieved through a reversible and fast sol-gel conversion mechanism. Remarkably, the supraMOF gel consists of 2D nanoplates of ZIF-8 with a reduced crystal symmetry.

引用

页码：8502 / 8505

页数：4

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