Synthesis of Chiral Thiazoline Ligands Tethered to a Sulfur Function and First Immobilization of a Thiazoline-Ligand

被引：10

作者：

Abrunhosa-Thomas, Isabelle ^{[1
]}

Betz, Alexander ^{[1
]}

Denance, Mickael ^{[1
]}

Dez, Isabelle ^{[1
]}

Gaumont, Annie-Claude ^{[1
]}

Gulea, Mihaela ^{[1
]}

机构：

[1] Univ Caen Basse Normandie, CNRS, ENSICAEN, Lab Chim Mol & Thioorgan,INC3M,FR 3038,UMR 6507, F-14050 Caen, France

来源：

HETEROATOM CHEMISTRY | 2010年 / 21卷 / 04期

关键词：

ASYMMETRIC ALLYLIC SUBSTITUTION; DIELS-ALDER REACTIONS; ENANTIOSELECTIVE CATALYSIS; BIS(OXAZOLINE) LIGANDS; BIS(THIAZOLINE); OXAZOLINES; PALLADIUM; EFFICIENT; DITHIOESTERS; SUPPORTS;

D O I：

10.1002/hc.20603

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of thiazoline ligands tethered to a sulfanyl or a sulfinyl group has been prepared using short and efficient reaction sequences. Among the different structures, one sulfanyl-thiazoline homopolymer was synthesized as a first example of an immobilized thiazoline ligand. The catalytic properties of these new ligands were evaluated in the Pd-catalyzed allylic substitution. (C) 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:242-249, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20603

引用

页码：242 / 249

页数：8

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