Crystal structure, magnetic properties, and second harmonic generation of a three-dimensional pyroelectric cyano-bridged Mn-Mo complex

被引:12
|
作者
Kosaka, Wataru
Nuida, Tomohiro
Hashimoto, Kazuhito
Ohkoshi, Shin-ichi
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1246/bcsj.80.960
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A paramagnetic pyroelectric 3-dimensional cyano-bridged assembly, [{Mn-II(H2O)(2)}{Mn-II(pyrazine)(H2O)(2)}-{Mo-IV(CN)(8)}]center dot 4H(2)O (P2(1)) was synthesized. This compound displayed second harmonic generation with a value of 6.0 x 10(-11) esu.
引用
收藏
页码:960 / 962
页数:3
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