Crystal structure, magnetic properties, and second harmonic generation of a three-dimensional pyroelectric cyano-bridged Mn-Mo complex

被引：12
|
作者：
Kosaka, Wataru
Nuida, Tomohiro
Hashimoto, Kazuhito
Ohkoshi, Shin-ichi
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2007年 / 80卷 / 05期
关键词：
D O I：
10.1246/bcsj.80.960
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A paramagnetic pyroelectric 3-dimensional cyano-bridged assembly, [{Mn-II(H2O)(2)}{Mn-II(pyrazine)(H2O)(2)}-{Mo-IV(CN)(8)}]center dot 4H(2)O (P2(1)) was synthesized. This compound displayed second harmonic generation with a value of 6.0 x 10(-11) esu.
引用
收藏
页码：960 / 962
页数：3
相关论文
共 50 条
  • [1] Crystal structure, magnetic properties, and second harmonic generation of a three-dimensional pyroelectric cyano-bridged Mn-Mo complex
    Kosaka, Wataru
    Nuida, Tomohiro
    Hashimoto, Kazuhito
    Ohkoshi, Shin-Ichi
    Bulletin of the Chemical Society of Japan, 2007, 80 (05): : 960 - 962
  • [2] Synthesis, crystal structure and magnetic properties of a new three-dimensional cyano-bridged Ni(II)-Mo(IV) complex
    Zhou, Hu
    Chen, Ying-Ying
    Yuan, Ai-Hua
    Shen, Xiao-Ping
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (04) : 363 - 366
  • [3] Synthesis, crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex of manganese(II) and molybdenum(IV)
    Shen, L
    Zhang, YJ
    Uiu, J
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (06) : 629 - 635
  • [4] Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex
    Karaagac, Dursun
    Kurkcuoglu, Gunes Suheyla
    Yesilel, Okan Zafer
    Hokelek, Tuncer
    Dal, Hakan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2012, 227 (09): : 639 - 645
  • [5] Electrochemical synthesis, crystal structure, and photomagnetic properties of a three-dimensional cyano-bridged copper-molybdenum complex
    Hozumi, T
    Hashimoto, K
    Ohkoshi, S
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) : 3864 - 3869
  • [6] A cyano-bridged Mn2IIICrIII complex: Synthesis, structure and magnetic properties
    Feng, Yuhua
    Wang, Chao
    Xu, Gongfeng
    Yan Ouyang
    Liao, Daizheng
    Yan, Shiping
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (03) : 341 - 344
  • [7] Crystal structure and nonlinear optical effect of a pyroelectric crystal composed of a cyano-bridged Cu-Mo assembly
    Hozumi, Toshiya
    Nuida, Tomohiro
    Hashimoto, Kazuhito
    Ohkoshi, Shin-ichi
    CRYSTAL GROWTH & DESIGN, 2006, 6 (08) : 1736 - 1737
  • [8] Lanthanide-ion-tuned magnetic properties in a series of three-dimensional cyano-bridged LnIIIWV assemblies
    Zhou, Hu
    Diao, Guo-Wang
    Qian, Su-Yan
    Yang, Xiao-Zhen
    Yuan, Ai-Hua
    Song, You
    Li, Yi-Zhi
    DALTON TRANSACTIONS, 2012, 41 (35) : 10690 - 10697
  • [9] Syntheses, crystal structures, and magnetic properties of cyano-bridged Mn(II)-Nb(IV) bimetal assemblies
    Nakagawa, Kosuke
    Imoto, Kenta
    Miyahara, Hiroyuki
    Ohkoshi, Shin-ichi
    POLYHEDRON, 2013, 52 : 424 - 428
  • [10] A bimetallic cyano-bridged complex based on nickel(II) and pentacyanidonitrosylferrate(II) precursors: characterization, crystal structure, and magnetic properties
    Pritha Talukder
    Shyamapada Shit
    Heinrich Nöth
    Matthias Westerhausen
    Alexander Nikolai Kneifel
    Samiran Mitra
    Transition Metal Chemistry, 2012, 37 : 71 - 77
12345