共 45 条
Waste Animal Bone as Support for CaO Impregnation in Catalytic Biodiesel Production from Vegetable Oil
被引:35
作者:
Ghanei, R.
[1
]
Dermani, R. Khalili
[1
]
Salehi, Y.
[1
]
Mohammadi, M.
[1
]
机构:
[1] Islamic Azad Univ, Farahan Branch, Dept Chem Engn, Farahan, Iran
关键词:
Transesterification;
Heterogeneous catalyst;
Hydroxyapatite;
Wet impregnation;
Calcium oxide;
Canola oil;
SOYBEAN OIL;
HETEROGENEOUS CATALYST;
PALM OIL;
PHYSICAL-PROPERTIES;
FRYING OIL;
TRANSESTERIFICATION;
SHELL;
OXIDE;
OPTIMIZATION;
CONVERSION;
D O I:
10.1007/s12649-015-9473-1
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Heterogeneous catalyst plays a vital role in this process, especially in view of cost and reusability. In the present study, a useless material such as waste animal bone was employed as support for calcium oxide impregnation. CaO was impregnated on the pre-treated waste sheep bone as an active component in different loading levels. The catalyst was then characterized and tested in reaction in similar conditions as follows: atmospheric pressure; reaction temperature: 60 A degrees C; methanol/oil molar ratio: 12:1; catalyst weight (based on oil weight): 5 % and reaction time: 5 h, under vigorous stirring. When 5 wt% of CaO, based on support weight was impregnated, maximum conversion of 95.18 % was obtained and also the catalyst was recoverable. On the other hand, conversion of 49.51 % was obtained when the same amount of CaO was used without support and the catalyst was also non-reusable. Moreover, reusability tests showed only a slight decrease in catalyst activity.
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页码:527 / 532
页数:6
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