Waste Animal Bone as Support for CaO Impregnation in Catalytic Biodiesel Production from Vegetable Oil

被引:35
作者
Ghanei, R. [1 ]
Dermani, R. Khalili [1 ]
Salehi, Y. [1 ]
Mohammadi, M. [1 ]
机构
[1] Islamic Azad Univ, Farahan Branch, Dept Chem Engn, Farahan, Iran
关键词
Transesterification; Heterogeneous catalyst; Hydroxyapatite; Wet impregnation; Calcium oxide; Canola oil; SOYBEAN OIL; HETEROGENEOUS CATALYST; PALM OIL; PHYSICAL-PROPERTIES; FRYING OIL; TRANSESTERIFICATION; SHELL; OXIDE; OPTIMIZATION; CONVERSION;
D O I
10.1007/s12649-015-9473-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Heterogeneous catalyst plays a vital role in this process, especially in view of cost and reusability. In the present study, a useless material such as waste animal bone was employed as support for calcium oxide impregnation. CaO was impregnated on the pre-treated waste sheep bone as an active component in different loading levels. The catalyst was then characterized and tested in reaction in similar conditions as follows: atmospheric pressure; reaction temperature: 60 A degrees C; methanol/oil molar ratio: 12:1; catalyst weight (based on oil weight): 5 % and reaction time: 5 h, under vigorous stirring. When 5 wt% of CaO, based on support weight was impregnated, maximum conversion of 95.18 % was obtained and also the catalyst was recoverable. On the other hand, conversion of 49.51 % was obtained when the same amount of CaO was used without support and the catalyst was also non-reusable. Moreover, reusability tests showed only a slight decrease in catalyst activity.
引用
收藏
页码:527 / 532
页数:6
相关论文
共 45 条
[1]   CaO supported on mesoporous silicas as basic catalysts for transesterification reactions [J].
Albuquerque, Monica C. G. ;
Jimenez-Urbistondo, Inmaculada ;
Santamaria-Gonzalez, Jose ;
Merida-Robles, Josefa M. ;
Moreno-Tost, Ramon ;
Rodriguez-Castellon, Enrique ;
Jimenez-Lopez, Antonio ;
Azevedo, Diana C. S. ;
Cavalcante, Celio L., Jr. ;
Maireles-Torres, Pedro .
APPLIED CATALYSIS A-GENERAL, 2008, 334 (1-2) :35-43
[2]   Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts:: Comparison with homogeneous NaOH [J].
Arzamendi, G. ;
Campo, I. ;
Arguinarena, E. ;
Sanchez, M. ;
Montes, M. ;
Gandia, L. M. .
CHEMICAL ENGINEERING JOURNAL, 2007, 134 (1-3) :123-130
[3]   Kinetics studies of synthesis of biodiesel from waste frying oil using a heterogeneous catalyst derived from snail shell [J].
Birla, Ashish ;
Singh, Bhaskar ;
Upadhyay, S. N. ;
Sharma, Y. C. .
BIORESOURCE TECHNOLOGY, 2012, 106 :95-100
[4]   Transesterification of palm oil with methanol to biodiesel over a KF/Al2O3 heterogeneous base catalyst [J].
Bo, Xu ;
Xiao, Guomin ;
Cui, Lingfeng ;
Wei, Ruiping ;
Gao, Lijing .
ENERGY & FUELS, 2007, 21 (06) :3109-3112
[5]   Catalysts derived from waste sources in the production of biodiesel using waste cooking oil [J].
Boey, Peng-Lim ;
Ganesan, Shangeetha ;
Maniam, Gaanty Pragas ;
Khairuddean, Melati .
CATALYSIS TODAY, 2012, 190 (01) :117-121
[6]   Biodiesel production via transesterification of palm olein using waste mud crab (Scylla serrata) shell as a heterogeneous catalyst [J].
Boey, Peng-Lim ;
Maniam, Gaanty Pragas ;
Abd Hamid, Shafida .
BIORESOURCE TECHNOLOGY, 2009, 100 (24) :6362-6368
[7]   A review on solid oxide derived from waste shells as catalyst for biodiesel production [J].
Boro, Jutika ;
Deka, Dhanapati ;
Thakur, Ashim J. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (01) :904-910
[8]   Solid oxide derived from waste shells of Turbonilla striatula as a renewable catalyst for biodiesel production [J].
Boro, Jutika ;
Thakur, Ashim J. ;
Deka, Dhanapati .
FUEL PROCESSING TECHNOLOGY, 2011, 92 (10) :2061-2067
[9]   Conversion of biomass to fuel: Transesterification of vegetable oil to biodiesel using KF loaded nano-γ-Al2O3 as catalyst [J].
Boz, Nezahat ;
Degirmenbasi, Nebahat ;
Kalyon, Dilhan M. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 89 (3-4) :590-596
[10]   Transesterification of soybean oil catalyzed by fly ash and egg shell derived solid catalysts [J].
Chakraborty, R. ;
Bepari, S. ;
Banerjee, A. .
CHEMICAL ENGINEERING JOURNAL, 2010, 165 (03) :798-805