Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln8Ge12} or {Ln11Ge12} Cage Cluster Building Blocks

被引：103

作者：

He, Huan ^{[1
]}

Cao, Gao-Juan ^{[1
]}

Zheng, Shou-Tian ^{[1
]}

Yang, Guo-Yu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 43期

关键词：

24-RING CHANNELS;

D O I：

10.1021/ja906735v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through the use of bis(carboxyethylgermanium) sesquioxide as the germanium source, lanthanide has been successfully introduced into germanate systems under hydrothermal conditions, resulting in a novel lanthanide germanate cluster organic framework with twofold-interpenetrating nets built from Nd8Ge12 cluster units. To avoid the interpenetration, a second ligand, 2-picolinic acid, was introduced into the above system, resulting in the formation of a series of noninterpenetrating networks constructed from Ln(11)Ge(12) cluster units, as expected.

引用

页码：15588 / +

页数：4

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