Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes

被引：0
|
作者：
Ansell, Melvyn B. [1 ]
Kostakis, George E. [1 ]
Navarro, Oscar [1 ,2 ]
Spencer, John [1 ]
机构：
[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England
[2] AMPAC Fine Chem, Highway 50 & Hazel Ave,Bldg 05-019, Rancho Cordova, CA 95741 USA
来源：
MOLECULES | 2021年 / 26卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
palladium; silicon; N-heterocyclic carbene; allylsilane; PINCER; REACTIVITY; HALIDES; LIGAND; PSIP; PD;
D O I：
10.3390/molecules26092460
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR3)(2)], where (SiR3 = SiMe3 and SiMe2Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR3)(Br)]. The structure of trans-[Pd(ITMe)(2)(SiMe2Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] Synthesis, Structural Studies and Reactivity of Two cis-Bis(phosphine)bis(silyl) Palladium(II) Complexes
    Wang, Lizhong
    Guo, Jinfei
    Li, Yajuan
    Su, Yanrong
    Liu, Jiawei
    Li, Yonghua
    Wang, Shi
    Shimada, Shigeru
    Huang, Wei
    CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (04) : 507 - 511
  • [2] trans-Difluoro Complexes of Palladium(II)
    Grushin, Vladimir V.
    Marshall, William J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) : 918 - +
  • [3] Trapping of two mononuclear silyl platinum(ii)/palladium(ii) complexes and a unique dinuclear bis(μ2-disilene)(silyl)nickel(ii) complex
    Song, Hao
    Zhang, Sen-Yu
    Gu, Peng-Fei
    Wu, Hua-Yu
    Wang, Zi-Kun
    Wang, Shi
    Wang, Zheng
    Gu, Yu-Yang
    Li, Yong-Hua
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (46) : 20351 - 20357
  • [4] Synthesis and Structures of Mono- and Trinuclear Complexes of Palladium(II) with 2-Chloropyridine
    I. A. Yakushev
    N. K. Ogarkova
    E. A. Sosunov
    M. Yu. Nesterenko
    E. K. Kultyshkina
    T. A. Tereshina
    A. S. Popova
    Journal of Structural Chemistry, 2023, 64 : 377 - 385
  • [5] SYNTHESIS AND STRUCTURES OF MONO- AND TRINUCLEAR COMPLEXES OF PALLADIUM(II) WITH 2-CHLOROPYRIDINE
    Yakushev, I. A.
    Ogarkova, N. K.
    Sosunov, E. A.
    Nesterenko, M. Yu.
    Kultyshkina, E. K.
    Tereshina, T. A.
    Popova, A. S.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2023, 64 (03) : 377 - 385
  • [6] Synthesis, Characterization and Biological Studies of Organoselenium trans-Palladium(II) Complexes
    Rakovic, Ivana
    Bogojeski, Jovana
    Mladenovic, Katarina
    Petrovic, Angelina
    Divac, Vera
    Mihailovic, Kristina
    Jovicic, Biljana Popovska
    Kostic, Marina
    Canovic, Predrag
    Milivojevic, Nevena
    Zivanovic, Marko
    Radojevic, Ivana
    MEDICINAL CHEMISTRY, 2021, 17 (09) : 1007 - 1022
  • [7] cis/trans Isomerization of Phosphinesulfonate Palladium(II) Complexes
    Conley, Matthew P.
    Jordan, Richard F.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (16) : 3744 - 3746
  • [8] Thermodynamic stability and acidic properties of platinum(II) and palladium(II) bromide complexes
    O. V. Salishcheva
    N. E. Moldagulova
    M. I. Gel’fman
    Russian Journal of Inorganic Chemistry, 2006, 51 : 683 - 686
  • [9] Synthesis and characterization of mono- and bi-nuclear palladium(II) and platinum(II) complexes containing acetamidine ligands
    Singhal, A
    Jain, VK
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1996, 74 (11): : 2018 - 2025
  • [10] Synthesis of palladium(II) and nickel(II) complexes with tetrabenzoporphine
    N. V. Chizhova
    A. O. Romanova
    Russian Journal of Inorganic Chemistry, 2007, 52 : 1713 - 1716
12345