1-Butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate as an efficient ligand for recoverable palladium-catalyzed Suzuki-Miyaura reaction in neat water

被引：15

作者：

Khosravi, Faezeh ^{[1
]}

Gholinejad, Mohammad ^{[1
,2
]}

Lledo, David ^{[3
]}

Grindlay, Guillermo ^{[3
]}

Najera, Carmen ^{[4
]}

Sansano, Jose M. ^{[4
,5
,6
]}

机构：

[1] IASBS, Dept Chem, POB 45195-1159, Gavazang 4513766731, Zanjan, Iran

[2] IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran

[3] Univ Alicante, Dept Analyt Chem Nutr & Food Sci, POB 99, E-03080 Alicante, Spain

[4] Univ Alicante, Fac Ciencias, Ctr Innovac Quim Avanzada ORFEO CINQA, E-03080 Alicante, Spain

[5] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

[6] Univ Alicante, Fac Ciencias, Inst Sintesis Organ, E-03080 Alicante, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2019年 / 901卷

基金：

美国国家科学基金会;

关键词：

Suzuki coupling; Biaryls; Palladium; Water; Green process; CROSS-COUPLING REACTION; ARYL BROMIDES; HETEROGENEOUS CATALYST; ORGANIC-REACTIONS; AQUEOUS-PHASE; NANOPARTICLES; COMPLEXES; PHOSPHINE; STABILIZATION; ALKYLPHOSPHINES;

D O I：

10.1016/j.jorganchem.2019.120941

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1-butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate is prepared and used as a water-soluble ligand in the Suzuki-Miyaura reaction. This ligand and palladium chloride generates a new active catalyst for the Suzuki coupling reaction between aryl iodides or bromides with arylboronic acids in neat water. This catalyst can be recycled and reused for the coupling reaction of 4-bromobenzonitrile with phenylboronic acid for at least six runs with low decreasing in catalytic activity. (C) 2019 Elsevier B.V. All rights reserved.

引用

页数：5

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