Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents

被引:133
作者
Sapountzis, I [1 ]
Lin, WW [1 ]
Kofink, CC [1 ]
Despotopoulou, C [1 ]
Knochel, P [1 ]
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
关键词
cross-coupling; homogeneous catalysis; iron; copper; magnesium;
D O I
10.1002/anie.200462013
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Well-matched couples: Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe-catalyzed cross-coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1654 / 1657
页数:4
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