Tris(4,4'-bipyrimidine)ruthenium(II) bis(hexafluorophosphate) acetone solvate

被引：8
作者：
Breu, J
Belser, P
Yersin, H
机构：
[1] UNIV FREIBURG, INST ANORGAN CHEM, CH-1700 FRIBOURG, SWITZERLAND
[2] UNIV REGENSBURG, INST PHYS CHEM, D-93040 REGENSBURG, GERMANY
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270195014156
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecular structure of tris(4,4'-bipyrimidine)ruthenium(II) {[Ru(bpm)(3)](2+)} in the title compound {[Ru(C8H6N4)(3)](PF6)(2).C3H6O} is similar to that of tris(2,2'-bipyridine)ruthenium(II) {[Ru(bpy)(3)](2+)}. However, replacement of C by N in the heterocyclic ring alters the molecular electrostatic potential of the complex cation and hence the chiral recognition and self-assembling, yielding a crystal-packing pattern that is unique among known structures of related trisdiimine-metal complexes.
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页码：858 / 861
页数：4
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