Crystal structures of poly(aryl ether) dendrons with palladium scorpionate complexes at their focal point

被引：20

作者：

Sanchez-Mendez, Alberto ^{[1
]}

de Jesus, Ernesto ^{[1
]}

Flores, Juan C. ^{[1
]}

Gomez-Sal, Pilar ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Inorgan, E-28871 Alcala De Henares, Spain

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 12期

关键词：

D O I：

10.1021/ic7005748

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel palladium( II) complexes with bis(pyrazol-1-yl) methane ligands at the focal point of G0-G3 poly(aryl ether)Frechet-type dendrons are reported. The molecular structures of the metallodendrimer series G0, G1, and G2 [(dend)CH(3,5-Me(2)pz)(2)(PdCl2)] have been determined by X-ray diffraction methods. The three structures show a similar three-dimensional organization of the metal complex, which is progressively engulfed by the branches with increasing dendrimer generation.

引用

页码：4793 / 4795

页数：3

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