Temperature effect on graphite KS44 lithiation in ethylene carbonate plus propylene carbonate solution: galvanostatic and impedance study

Graphite Lonza KS44 in a solution 1 M LiClO4 in a propoylene carbonate + ethylene carbonate (1 M: 1 M) mixture was lithiated and delithiated galvanostatically at room temperature and at the elevated temperature of 55 degreesC. Voltage-time profiles and complex impedance diagrams were recorded and are discussed for this particular system. It was confirmed that this type of graphite shows a relatively small current loss consumed by exfoliation, if lithiated at room temperature. However, the voltage-time curve of the first charging at 55 degreesC shows a long voltage plateau at 0.7 V vs. Li/Li+ which corresponds to 540 mAh g(-1) of irreversible capacity attributed to exfoliation. The solid electrolyte layer formed at elevated temperature,. although less protecting in the sense of electrolyte reduction, shows a remarkably higher electrical resistance than that formed at room temperature. A comparison of the impedance diagrams of lithiated and delithiated samples allows the conclusion that mass transfer through the graphite. not that through the solid electrolyte layer, plays a dominant role in the mass transfer limitations.