RAFT dispersion polymerization induced self-assembly (PISA) of boronic acid-substituted acrylamides

被引：9
|
作者：
Dhiraj, Harpal S. [1 ]
Ishizuka, Fumi [2 ]
Elshaer, Amr [1 ]
Zetterlund, Per B. [2 ]
Aldabbagh, Fawaz [1 ]
机构：
[1] Kingston Univ, Sch Life Sci Pharm & Chem, Dept Pharm, Penrhyn Rd, Kingston Upon Thames KT1 2EE, Surrey, England
[2] Univ New South Wales, Sch Chem Engn, Cluster Adv Macromol Design CAMD, Sydney, NSW 2052, Australia
来源：
POLYMER CHEMISTRY | 2022年 / 13卷 / 25期
关键词：
MORPHOLOGIES; COPOLYMERS;
D O I：
10.1039/d2py00530a
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization induced self-assembly (PISA) of boronic acid (BA)-substituted acrylamides is established. The first PISA on unprotected BA-substituted monomer yields spherical nanoparticles (NPs) that undergo room-temperature transitions to higher order morphologies upon dilution with the dispersion solvent. PISA with the BA pinacol ester-derivative yields spherical NPs, worms, and vesicles.
引用
收藏
页码：3750 / 3755
页数：6
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