Tetrazoles: XLVII. A route to tetrazole-containing dendrimers

被引:10
作者
Artamonova, TV [1 ]
Zatsepina, MV [1 ]
Koldobskii, GI [1 ]
机构
[1] St Petersburg State Inst Technol, St Petersburg 190013, Russia
关键词
D O I
10.1007/s11178-005-0013-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 5-methylsulfonyl-1-phenyltetrazole with pentaerythritol in acetonitrile in the presence of sodium hydroxide gave tetrakis(1-phenyltetrazol-5-yloxymethyl)methane. Sulfur-containing analog of the latter was obtained by alkylation of 1-phenyl-4,5-dihydrotetrazole-5-thione with 1,3-dibromo-2,2-bis-(bromomethyl)propane. Nitration of the resulting polytetrazoles afforded the corresponding tetrakis(p-nitrophenyl) derivatives which can be used in the synthesis of tetrazole-containing dendrimers according to the divergent scheme.
引用
收藏
页码:1318 / 1321
页数:4
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