An improved procedure for the conversion of alkenes and glycals to 1,2-diazides using Mn(OAc)3•2H2O in acetonitrile containing trifluoroacetic acid

被引：67

作者：

Snider, BB ^{[1
]}

Lin, H ^{[1
]}

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02254 USA

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 10期

关键词：

D O I：

10.1080/00397919808007024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkenes and Glycals react with Mn(OAc3).2H(2)O and NaN3 in 9:1 acetonitrile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn(OAc)(3).H2O and Cu(OAc)(2).

引用

页码：1913 / 1922

页数：10

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