Extremely thin absorber layer solar cells on zinc oxide nanorods by chemical spray

被引:66
作者
Krunks, M. [1 ]
Karber, E. [1 ]
Katerski, A. [1 ]
Otto, K. [1 ]
Acik, I. Oja [1 ]
Dedova, T. [1 ]
Mere, A. [1 ]
机构
[1] Tallinn Univ Technol, Dept Mat Sci, EE-19086 Tallinn, Estonia
关键词
ETA-cell; Chemical spray pyrolysis; ZnO nanorods; Indium sulfide; Copper indium disulfide; PYROLYSIS; PERFORMANCE; DEPOSITION;
D O I
10.1016/j.solmat.2010.02.036
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
ZnO(rod)/In(2)S(3)/CuInS(2) type ETA-cells were prepared by in-line chemical spray pyrolysis method. Effects of buffer layer thickness and ZnO nanorod length (500-1000 nm) were studied by means of SEM, I-V dependencies and EQE spectra. Conformal layer of In(2)S(3), obtained by spray of solution with pH=4.8, effectively protects ZnO nanorods from dissolution during the spray of acidic solutions. Increasing In(2)S(3) layer thickness reduces fluctuations of the cell output parameters, and increases V(OC) and FF; however, at certain thickness induces losses due to light absorption. The highest conversion efficiency 4.17% at AM1.5 was recorded from small contact area of the cell based on rods with length of 600 nm. Perspectives for further development are discussed. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1191 / 1195
页数:5
相关论文
共 12 条
[1]   Growth of ultra-thin TiO2 films by spray pyrolysis on different substrates [J].
Acik, I. Oja ;
Junolainen, A. ;
Mikli, V. ;
Danilson, M. ;
Krunks, M. .
APPLIED SURFACE SCIENCE, 2009, 256 (05) :1391-1394
[2]   Nanostructured solar cell by spray pyrolysis: Effect of titania barrier layer on the cell performance [J].
Acik, I. Oja ;
Katerski, A. ;
Mere, A. ;
Aarik, J. ;
Aidla, A. ;
Dedova, T. ;
Krunks, M. .
THIN SOLID FILMS, 2009, 517 (07) :2443-2447
[3]   Influence of the local absorber layer thickness on the performance of ZnO nanorod solar cells [J].
Belaidi, Abdelhak ;
Dittrich, Thomas ;
Kieven, David ;
Tornow, Julian ;
Schwarzburg, Klaus ;
Lux-Steiner, Martha .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2008, 2 (04) :172-174
[4]   ZnO nanorods via spray deposition of solutions containing zinc chloride and thiocarbamide [J].
Dedova, Tatjana ;
Volobujeva, Olga ;
Klauson, Jelena ;
Mere, Arvo ;
Krunks, Malle .
NANOSCALE RESEARCH LETTERS, 2007, 2 (08) :391-396
[5]   Sb2S3-Sensitized Nanoporous TiO2 Solar Cells [J].
Itzhaik, Yafit ;
Niitsoo, Olivia ;
Page, Miles ;
Hodes, Gary .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (11) :4254-4256
[6]   Effect of internal surface area on the performance of ZnO/In2S3/CuSCN solar cells with extremely thin absorber [J].
Kieven, D. ;
Dittrich, T. ;
Belaidi, A. ;
Tornow, J. ;
Schwarzburg, K. ;
Allsop, N. ;
Lux-Steiner, M. .
APPLIED PHYSICS LETTERS, 2008, 92 (15)
[7]   Nanostructured solar cell based on spray pyrolysis deposited ZnO nanorod array [J].
Krunks, M. ;
Katerski, A. ;
Dedova, T. ;
Acik, I. Oja ;
Mere, A. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (09) :1016-1019
[8]   Spray pyrolysis deposition of zinc oxide nanostructured layers [J].
Krunks, M. ;
Dedova, T. ;
Acik, I. Oja .
THIN SOLID FILMS, 2006, 515 (03) :1157-1160
[9]   CdSe-Sensitized p-CuSCN/nanowire n-ZnO heterojunctions [J].
Lévy-Clément, C ;
Tena-Zaera, R ;
Ryan, MA ;
Katty, A ;
Hodes, G .
ADVANCED MATERIALS, 2005, 17 (12) :1512-1515
[10]   A parametric study of TiO2/CuInS2 nanocomposite solar cells:: how cell thickness, buffer layer thickness, and TiO2 particle size affect performance [J].
O'Hayre, Ryan ;
Nanu, Marian ;
Schoonman, Joop ;
Goossens, Albert .
NANOTECHNOLOGY, 2007, 18 (05)