SnI4•(S8)2: A Novel Adduct-Type Infrared Second-Order Nonlinear Optical Crystal

被引：172

作者：

Guo, Sheng-Ping ^{[1
]}

Chi, Yang ^{[1
]}

Xue, Huai-Guo ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, 180 Siwangting Rd, Yangzhou 250002, Jiangsu, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 36期

基金：

中国国家自然科学基金;

关键词：

nonlinear optical materials; second-order nonlinear optics; solid-state reaction; sulfur; tin; 2ND-HARMONIC GENERATION; ADDITION COMPLEX; CO-CRYSTAL; CHALCOHALIDES; CS; TRIIODIDE; SULFUR; IODIDE; SERIES; MIDDLE;

D O I：

10.1002/anie.201803482

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple adduct from tin tetraiodide SnI4 and octasulfur S-8, SnI4 center dot(S-8)(2) (1), is obtained employing a facile reaction. The combination of Sn4+ ions with d(10) electron configuration, acentric SnI4 tetrahedra, and lone-pair effects of S-8, makes 1 a phase-matchable infrared NLO crystal with a moderate second-harmonic generation (SHG) response and a very high laser-induced damage threshold (LIDT), which is well confirmed by the DFT calculations.

引用

页码：11540 / 11543

页数：4

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