Preparation and characterization of Ni(dpedt)(pddt) and Ni(dpedt)(pddt)•CS2, where dpedt is diphenylethylenedithiolate and pddt is 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate

被引：5

作者：

Anyfantis, George C. ^{[1
]}

Papavassiliou, George C. ^{[1
]}

Terzis, Aris ^{[2
]}

Raptopoulou, Catherine P. ^{[2
]}

Psycharis, Vassilis ^{[2
]}

Paraskevopoulou, Patrina ^{[3
]}

机构：

[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, Athens 11635, Greece

[2] NCSR, Inst Mat Sci, Athens 15310, Greece

[3] Panepistimioupoli Zografou, Fac Chem, Dept Inorgan Chem, Athens 15771, Greece

来源：

POLYHEDRON | 2010年 / 29卷 / 03期

关键词：

Metal 1,2-dithiolenes; Crystal structure; Optical properties; Redox properties; METAL-DITHIOLENE COMPLEXES; NICKEL 1,2-DITHIOLENE COMPLEXES; FIELD-EFFECT TRANSISTORS; MOLECULAR-METALS; DYES; M=NI; ABSORPTION; M(DMIT)(2); R; R'TIMDT; ELECTRON;

D O I：

10.1016/j.poly.2009.11.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsymmetrical nickel 1,2-dithiolene complex based oil diphenylethylenedithiolate (dpedt) and 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate (pddt) was prepared and characterized Depending on the conditions of crystallization, it is possible to obtain the complex in two different crystalline forms X-ray structure studies recognize these forms as Ni(dpedt)(pddt) and Ni(dpedt)(pddt) CS2 The experimental optical and electrochemical parameters are in a good agreement with the calculated ones. using the corresponding parameters of the symmetrical complexes. Ni(dpedt)(2) and Ni(pddt)(2). The HOMO and LUMO energy levels, obtained from optical and electrochemical measurements, are very close to the Fermi energy of (metallic) Au The chemical and electrochemical properties of both forms showed that they ale stable in air and could be candidate materials for optics and electronics (C) 2009 Published by Elsevier Ltd.

引用

页码：969 / 974

页数：6

共 68 条

[1] Transient nonlinear optical response of novel neutral unsymmetrical nickel dithiolene complexes [J].

Aloukos, P. ;

Couris, S. ;

Koutselas, J. B. ;

Anyfantis, G. C. ;

Papavassiliou, G. C. .

CHEMICAL PHYSICS LETTERS, 2006, 428 (1-3) :109-113

[2]

[Anonymous], 2005, CRYST CLEAR

[3] Air-stable ambipolar organic transistors [J].

Anthopoulos, Thomas D. ;

Anyfantis, G. C. ;

Papavassiliou, G. C. ;

de Leeuw, Dago M. .

APPLIED PHYSICS LETTERS, 2007, 90 (12)

[4] Air-stable complementary-like circuits based on organic ambipolar transistors [J].

Anthopoulos, Thomas D. ;

Setayesh, Sepas ;

Smits, Edsger ;

Colle, Michael ;

Cantatore, Eugenio ;

de Boer, Bert ;

Blom, Paul W. M. ;

de Leeuw, Dago M. .

ADVANCED MATERIALS, 2006, 18 (14) :1900-+

[5] Preparation and characterization of some nickel 1,2-dithiolene complexes as single-component semiconductors [J].

Anyfantis, G. C. ;

Papavassiliou, G. C. ;

Terzis, A. ;

Raptopoulou, C. P. ;

Weng, Y. F. ;

Yoshino, H. ;

Murata, K. .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2006, 61 (08) :1007-1011

[6] Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics [J].

Anyfantis, George C. ;

Papavassiliou, George C. ;

Assimomytis, Nikos ;

Terzis, Aris ;

Psycharis, Vassilis ;

Raptopoulou, Catherine P. ;

Kyritsis, Panayotis ;

Thoma, Vladimiros ;

Koutselas, Ioannis B. .

SOLID STATE SCIENCES, 2008, 10 (12) :1729-1733

[7] New [M(R,R′timdt)2] metal-dithiolenes and related compounds (M = Ni, Pd, Pt;: R,R′timdt = monoanion of disubstituted imidazolidine-2,4,5-trithiones):: An experimental and theoretical investigation [J].

Aragoni, MC ;

Arca, M ;

Demartin, F ;

Devillanova, FA ;

Garau, A ;

Isaia, F ;

Lelj, F ;

Lippolis, V ;

Verani, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (30) :7098-7107

[8] [M(R-dmet)2] bis(1,2-dithiolenes):: a promising new class intermediate between [M(dMit)2] and [M(R,R′-timdt)2] (M=Ni, Pd, Pt) [J].

Aragoni, MC ;

Arca, M ;

Devillanova, FA ;

Isaia, F ;

Lippolis, V ;

Mancini, A ;

Pala, L ;

Slawin, AMZ ;

Woollins, JD .

INORGANIC CHEMISTRY, 2005, 44 (26) :9610-9612

[9] NIR dyes based on [M(R,R′timdt)2] metal-dithiolenes:: Additivity of M, R, and R′ contributions to tune the NIR absorption (M = Ni, Pd, Pt; R,R′timdt = monoreduced form of disubstituted imidazolidine-2,4,5-trithione) [J].

Aragoni, MC ;

Arca, M ;

Cassano, T ;

Denotti, C ;

Devillanova, FA ;

Frau, R ;

Isaia, F ;

Lelj, F ;

Lippolis, V ;

Nitti, L ;

Romaniello, P ;

Tommasi, R ;

Verani, G .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (10) :1939-1947

[10] Photoinduced conductivity and nonlinear optical properties of [M(R, R′timdt)2] dithiolenes (M = Ni, Pd, Pt; R,R′timdt = monoreduced imidazolidine-2,4,5-trithione) as materials for optically driven switches and photodetectors [J].

Aragoni, MC ;

Arca, M ;

Cassano, T ;

Denotti, C ;

Devillanova, FA ;

Isaia, F ;

Lippolis, V ;

Natali, D ;

Nitti, L ;

Sampietro, M ;

Tommasi, R ;

Verani, G .

INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (10) :869-872

← 1 2 3 4 5 6 7 →