Structure and Intermolecular Interactions in Aqueous Solutions of Polyethylene Glycol

被引：14

作者：

Almasy, Laszlo ^{[1
,2
]}

Artykulnyi, Oleksandr P. ^{[3
]}

Petrenko, Viktor, I ^{[4
,5
]}

Ivankov, Oleksandr I. ^{[3
]}

Bulavin, Leonid A. ^{[3
]}

Yan, Minhao ^{[1
]}

Haramus, Vasil M. ^{[6
]}

机构：

[1] Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China

[2] Inst Energy Secur & Environm Safety, Ctr Energy Res, Konkoly Thege Miklos Ut 29-33, H-1121 Budapest, Hungary

[3] Taras Shevchenko Kyiv Natl Univ, Fac Phys, UA-01601 Kiev, Ukraine

[4] Basque Ctr Mat Applicat & Nanostruct, BCMat, Leioa 48940, Spain

[5] Basque Fdn Sci, Ikerbasque, Bilbao 48009, Spain

[6] Helmholtz Zentrum Hereon, Max Planck St 1, D-21502 Geesthacht, Germany

来源：

MOLECULES | 2022年 / 27卷 / 08期

关键词：

polymers in solutions; poly(ethylene glycol); micelle; Gaussian chain; small-angle neutron scattering; POLY(ETHYLENE GLYCOL); MICELLAR-SOLUTIONS; DRUG-DELIVERY; SODIUM OLEATE; IONIC LIQUID; SCATTERING; NANOPARTICLES; OXIDE); IMPACT; SANS;

D O I：

10.3390/molecules27082573

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Aqueous solutions of polyethylene glycol are studied by small-angle neutron scattering over a broad range of polymer molecular masses and concentrations. The scattering data were modeled by a Gaussian chain form factor combined with random phase approximation, which provided good fits over the whole studied concentration range. The results showed that polyethylene glycol in the molecular mass range 0.4-20 kDa in water at physiological temperature T = 37 degrees C behaves like a random coil in nearly theta solvent conditions. The obtained results serve as a reference for the description of complex mixtures with PEG used in various applications.

引用

页数：9

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