A luminescent zinc-anthracene-ditetrazolate coordination polymer material constructed from {Zn4} ring SBU involving in situ ligand synthesis

被引：3

作者：

Ma, Hui-Yan

Wang, Su-Na

Yao, Qing-Xia

Li, Da-Cheng

Li, Yun-Wu ^{[1
]}

Dou, Jian-Min ^{[1
]}

机构：

[1] Liaocheng Univ, Sch Mat Sci & Engn, Liaocheng 252000, Peoples R China

来源：

MATERIALS LETTERS | 2016年 / 179卷

关键词：

Coordination polymer; In situ ligand synthesis; Crystal structure; Luminescence; METAL-ORGANIC FRAMEWORKS; MODULATION; WATER; SIZE; CO2;

D O I：

10.1016/j.matlet.2016.05.057

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

One novel coordination polymer, [Zn-2(L)(bPP)(Cl)(2)](n) (1) (H2L=9,10-di-(1H-tetrazole-5-yl) anthracene, bpp=1,3-bis(4-pyridyl) propane), has been constructed by in situ ligands synthesis system. The formation of ditetrazole-based ligand H2L involves the in situ Sharpless [2+3] cycloaddition reaction between 9,10-dicyanoanthracene (DCA) and NaN3 in the presence of Zn2+ ions as Lewis-acid catalysts under solvothermal conditions. At the same time, the bpp ligand is introduced to adjust the structure of 1. Compound 1 exhibits an 8-connected three-dimensional (3D) bcu (body centered cubic) topology constructed from rhombic tetrameric {Zn-4} rings as secondary building units (SBUs). Moreover, the luminescent properties of 1 have been also investigated. (C) 2016 Elsevier B.V. All rights reserved.

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页码：24 / 26

页数：3

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