Liquid-phase Fischer-Tropsch synthesis over Fe nanoparticles dispersed in polyethylene glycol (PEG)

被引:41
作者
Fan, Xiao-Bing [1 ]
Tao, Zhi-Yuan [1 ]
Xiao, Chao-Xian [1 ]
Liu, Fang [1 ]
Kou, Yuan [1 ]
机构
[1] Peking Univ, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
IONIC LIQUIDS; CATALYSTS;
D O I
10.1039/b926397g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Fe nanoparticles dispersed in polyethylene glycol (PEG) can catalyze Fischer-Tropsch (F-T) synthesis at mild conditions (150 degrees C, 2.0 MPa H-2, 1.0 MPa CO) with an activity as high as 1.5 mol(CO) mol(Fe)(-1) h(-1). The F-T products, hydrocarbons, are insoluble in the green solvent PEG, and could be easily separated from the reaction mixture.
引用
收藏
页码:795 / 797
页数:3
相关论文
共 50 条
[21]   Highly dispersed cobalt on N-doped carbon nanotubes with improved Fischer-Tropsch synthesis activity [J].
Fu, Tingjun ;
Li, Zhenhua .
CATALYSIS COMMUNICATIONS, 2014, 47 :54-57
[22]   Fischer-Tropsch synthesis over alumina supported cobalt catalyst: Effect of crystal phase and pore structure of alumina support [J].
Shimura, Katsuya ;
Miyazawa, Tomohisa ;
Hanaoka, Toshiaki ;
Hirata, Satoshi .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 394 :22-32
[23]   Cobalt-Based Catalysts for Selective Synthesis of Clean Liquid Fuel via Fischer-Tropsch Synthesis [J].
Shao Yan ;
Yao Nan ;
Lu Chunshan ;
Lv Deyi ;
Liu Huazhang ;
Li Xiaonian .
PROGRESS IN CHEMISTRY, 2010, 22 (10) :1911-1920
[24]   Role of mesopores in Co/ZSM-5 for the direct synthesis of liquid fuel by Fischer-Tropsch synthesis [J].
Min, Ji-Eun ;
Kim, Sungtak ;
Kwak, Geunjae ;
Kim, Yong Tae ;
Han, Seung Ju ;
Lee, Yunjo ;
Jun, Ki-Won ;
Kim, Seok Ki .
CATALYSIS SCIENCE & TECHNOLOGY, 2018, 8 (24) :6346-6359
[25]   Bimetallic Cobalt Nanoparticles (Co-M): Synthesis, Characterization, and Application in the Fischer-Tropsch Process [J].
Ralston, Walter T. ;
Liu, Wen-Chi ;
Alayoglu, Selim ;
Melaet, Gerome .
TOPICS IN CATALYSIS, 2018, 61 (9-11) :1002-1015
[26]   The role of bulk H and C species in the chain lengthening of Fischer-Tropsch synthesis over nickel [J].
Barbier, A ;
Pereira, EB ;
Martin, GA .
CATALYSIS LETTERS, 1997, 45 (3-4) :221-226
[27]   Fischer-Tropsch synthesis: effect of silica on hydrocarbon production over cobalt-based catalysts [J].
Yaghoobpour, Elham ;
Zamani, Yahya ;
Zarrinpashne, Saeed ;
Zamaniyan, Akbar .
CHEMICAL PAPERS, 2019, 73 (01) :205-214
[28]   Effective activation of montmorillonite and its application for Fischer-Tropsch synthesis over ruthenium promoted cobalt [J].
Zhao, Yong-Hua ;
Wang, Yan-Jiao ;
Hao, Qing-Qing ;
Liu, Zhao-Tie ;
Liu, Zhong-Wen .
FUEL PROCESSING TECHNOLOGY, 2015, 136 :87-95
[29]   Fischer-Tropsch Synthesis over Ru Catalysts by Using Syngas Derived from Woody Biomass [J].
Okabe, Kiyomi ;
Murata, Kazuhisa ;
Nakanishi, Masakazu ;
Ogi, Tomoko ;
Nurunnabi, Mohammad ;
Liu, Yangyong .
CATALYSIS LETTERS, 2009, 128 (1-2) :171-176
[30]   Effect of the Polymeric Stabilizer in the Aqueous Phase Fischer-Tropsch Synthesis Catalyzed by Colloidal Cobalt Nanocatalysts [J].
Delgado, Jorge A. ;
Claver, Carmen ;
Castillon, Sergio ;
Curulla-Ferre, Daniel ;
Godard, Cyril .
NANOMATERIALS, 2017, 7 (03)