Liquid-phase Fischer-Tropsch synthesis over Fe nanoparticles dispersed in polyethylene glycol (PEG)

被引：41

作者：

Fan, Xiao-Bing ^{[1
]}

Tao, Zhi-Yuan ^{[1
]}

Xiao, Chao-Xian ^{[1
]}

Liu, Fang ^{[1
]}

Kou, Yuan ^{[1
]}

机构：

[1] Peking Univ, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 05期

基金：

中国国家自然科学基金;

关键词：

IONIC LIQUIDS; CATALYSTS;

D O I：

10.1039/b926397g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Fe nanoparticles dispersed in polyethylene glycol (PEG) can catalyze Fischer-Tropsch (F-T) synthesis at mild conditions (150 degrees C, 2.0 MPa H-2, 1.0 MPa CO) with an activity as high as 1.5 mol(CO) mol(Fe)(-1) h(-1). The F-T products, hydrocarbons, are insoluble in the green solvent PEG, and could be easily separated from the reaction mixture.

引用

页码：795 / 797

页数：3

共 24 条

[1] Controlling synthesis of Fe nanoparticles with polyethylene glycol [J].

Bonder, M. J. ;

Zhang, Y. ;

Kiick, K. L. ;

Papaefthymiou, V. ;

Hadjipanayis, G. C. .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 311 (02) :658-664

[2] Polyethylene glycol and solutions of polyethylene glycol as green reaction media [J].

Chen, J ;

Spear, SK ;

Huddleston, JG ;

Rogers, RD .

GREEN CHEMISTRY, 2005, 7 (02) :64-82

[3] Effect of confinement in carbon nanotubes on the activity of Fischer-Tropsch iron catalyst [J].

Chen, Wei ;

Fan, Zhongli ;

Pan, Xiulian ;

Bao, Xinhe .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (29) :9414-9419

[4] Fischer-Tropsch refining: technology selection to match molecules [J].

de Klerk, Arno .

GREEN CHEMISTRY, 2008, 10 (12) :1249-1279

[5] One-Step Synthesis of 2-Alkyl-dioxolanes from Ethylene Glycol and Syngas [J].

Fan, Xiao-Bing ;

Yan, Ning ;

Tao, Zhi-Yuan ;

Evans, David ;

Xiao, Chao-Xian ;

Kou, Yuan .

CHEMSUSCHEM, 2009, 2 (10) :941-943

[6] Synthesis, properties, and applications of iron nanoparticles [J].

Huber, DL .

SMALL, 2005, 1 (05) :482-501

[7] Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels [J].

Khodakov, Andrei Y. ;

Chu, Wei ;

Fongarland, Pascal .

CHEMICAL REVIEWS, 2007, 107 (05) :1692-1744

[8] The role of electrophilic species in the Fischer-Tropsch reaction [J].

Maitlis, Peter M. ;

Zanotti, Valerio .

CHEMICAL COMMUNICATIONS, 2009, (13) :1619-1634

[9] Rhodium nanoparticles stabilized by ionic copolymers in ionic liquids: Long lifetime nanocluster catalysts for benzene hydrogenation [J].

Mu, XD ;

Meng, JQ ;

Li, ZC ;

Kou, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) :9694-9695

[10] Activation study of precipitated iron Fischer-Tropsch catalysts [J].

OBrien, RJ ;

Xu, LG ;

Spicer, RL ;

Davis, BH .

ENERGY & FUELS, 1996, 10 (04) :921-926

← 1 2 3 →