Superior electrical, mechanical and electromagnetic interference shielding properties of polycarbonate/ethylene-methyl acrylate-in situ reduced graphene oxide nanocomposites

被引:20
作者
Bagotia, Nisha [1 ]
Choudhary, Veena [2 ]
Sharma, D. K. [1 ]
机构
[1] Indian Inst Technol Delhi, Ctr Energy Studies, New Delhi 123001, India
[2] Indian Inst Technol Delhi, Dept Mat Sci & Engn, New Delhi 123001, India
关键词
THERMAL REDUCTION; CARBON NANOTUBES; COMPOSITE FILMS; GRAPHITE OXIDE; CONDUCTIVITY; EXFOLIATION; CHEMISTRY; COVALENT;
D O I
10.1007/s10853-018-2749-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fabrication of the polymer/graphene nanocomposites with high electro-mechanical properties is very challenging approach these days against the electromagnetic pollution. This paper mainly focused on the preparation of in situ reduced graphene oxide (IrGO) during melt blending of polycarbonate/ethylene-methyl acrylate [PC/EMA (95/5 wt/wt)] blend and graphene oxide to achieve enhanced electro-mechanical properties of the nanocomposites. It involves the reduction mechanism of graphene oxide with in the polymer matrix. The nanocomposites showed a significant improvement in mechanical stiffness owing to efficient stress transfer from matrix to filler. PC/EMA-IrGO nanocomposites with 15 phr loading of GO showed highest electromagnetic shielding effectiveness (- 30 dB) over the frequency range of X-band (8.2-12.4 GHz). This promising strategy of developing single-step PC/EMA-IrGO nanocomposites with enhanced electro-mechanical properties can also be used in large-scale technical and commercial applications.
引用
收藏
页码:16047 / 16061
页数:15
相关论文
共 54 条
[21]   Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity [J].
Kim, Hyunwoo ;
Miura, Yutaka ;
Macosko, Christopher W. .
CHEMISTRY OF MATERIALS, 2010, 22 (11) :3441-3450
[22]   Synergistic effects of carbon fillers on shielding effectiveness in conductive nylon 6,6-and polycarbonate-based resins [J].
Krueger, QJ ;
King, JA .
ADVANCES IN POLYMER TECHNOLOGY, 2003, 22 (02) :96-111
[23]   Effects of morphology on the electrical and mechanical properties of the polycarbonate/multi-walled carbon nanotube composites [J].
Kum, Chong Ku ;
Sung, Yu-Taek ;
Han, Mi Sun ;
Kim, Woo Nyon ;
Lee, Heon Sang ;
Lee, Sun-Jeong ;
Joo, Jinsoo .
MACROMOLECULAR RESEARCH, 2006, 14 (04) :456-460
[24]   Tunable color generation of transparent composite films reinforced with luminescent nanofillers [J].
Lee, Byung-Il ;
Jeong, Heejin ;
Byeon, Song-Ho .
CHEMICAL COMMUNICATIONS, 2013, 49 (97) :11397-11399
[25]   Electrical conductivity of thermally reduced graphene oxide/polymer composites with a segregated structure [J].
Li, Mengkai ;
Gao, Chunxiao ;
Hu, Hongliang ;
Zhao, Zhudi .
CARBON, 2013, 65 :371-373
[26]   Electromagnetic interference (EMI) shielding of single-walled carbon nanotube epoxy composites [J].
Li, Ning ;
Huang, Yi ;
Du, Feng ;
He, Xiaobo ;
Lin, Xiao ;
Gao, Hongjun ;
Ma, Yanfeng ;
Li, Feifei ;
Chen, Yongsheng ;
Eklund, Peter C. .
NANO LETTERS, 2006, 6 (06) :1141-1145
[27]   Infrared-Triggered Actuators from Graphene-Based Nanocomposites [J].
Liang, Jiajie ;
Xu, Yanfei ;
Huang, Yi ;
Zhang, Long ;
Wang, Yan ;
Ma, Yanfeng ;
Li, Feifei ;
Guo, Tianying ;
Chen, Yongsheng .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (22) :9921-9927
[28]   Graphene-based materials for energy applications [J].
Liu, Jun ;
Xue, Yuhua ;
Zhang, Mei ;
Dai, Liming .
MRS BULLETIN, 2012, 37 (12) :1265-1272
[29]   Preparation of polyester/reduced graphene oxide composites via in situ melt polycondensation and simultaneous thermo-reduction of graphene oxide [J].
Liu, Kai ;
Chen, Li ;
Chen, Yao ;
Wu, Jieli ;
Zhang, Weiyi ;
Chen, Feng ;
Fu, Qiang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (24) :8612-8617
[30]  
Ovid'ko IA, 2013, REV ADV MATER SCI, V34, P1