Dynamic opic-pryce effect in 59Co NQR spectra of compounds R1R2R3SnCo(CO)4

被引:0
|
作者
Semin, G. K. [1 ]
Bryukhova, E. V. [1 ]
Raevskii, A. M. [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 12期
关键词
D O I
10.1134/S0036024406120338
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The parameters of the equation relating the quadrupole coupling constant (e(2) Qq (zz) ) to the asymmetry parameter (eta) of Co-59 in the series of compounds R1R2R3SnCo(CO)(4) and in the series of reference compounds R1R2R3GeCo(CO)(4) and [(pi-C5H5-n Me-n)Co(CO)(2)](2) are determined. The mean correlation times are determined for the complete electron tunneling in the dispersion region of electron-nuclear motions (eta(0) +/- triangle eta).
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页码:2054 / 2057
页数:4
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