A Novel 3D Metal Coordination Polymer Based on Tetranuclear Zinc Cluster Building Blocks: Syntheses, Structures and Photoluminescent Property

被引：6

作者：

Lu, Jiu-Fu ^{[1
,2
]}

Liu, Zhi-Hong ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Peoples R China

[2] Shaanxi Univ Technol, Chem Engn Coll, Hanzhong 723001, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Hydrothermal synthesis; Structure; Zn(II) Clusters; Photoluminescent property; ORGANIC FRAMEWORKS; MIXED-LIGANDS; COMPLEXES; DESIGN; ACID;

D O I：

10.1007/s10876-015-0950-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 3D metal coordination polymer (MCP), {[Zn-2(A mu(3)-OH)(btc)(bmip)]center dot H2O}(n) (1), where H(3)btc = 1,3,5-benzenetricarboxylate acid, bmip = 1,3-bis(2-methylimidazolyl)propane, was synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. Single crystal X-ray analysis revealed that MCP 1 features a 3D framework based on tetranuclear Zn(II) Clusters where the four zinc ions are coplanar, and shows an unusual binodal (3,10)-connected topology. Furthermore, the photoluminescent property of MCP 1 was investigated at room temperature. [GRAPHICS] .

引用

页码：573 / 582

页数：10

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