A Novel 3D Metal Coordination Polymer Based on Tetranuclear Zinc Cluster Building Blocks: Syntheses, Structures and Photoluminescent Property

被引：6
作者：
Lu, Jiu-Fu [1 ,2 ]
Liu, Zhi-Hong [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Peoples R China
[2] Shaanxi Univ Technol, Chem Engn Coll, Hanzhong 723001, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Structure; Zn(II) Clusters; Photoluminescent property; ORGANIC FRAMEWORKS; MIXED-LIGANDS; COMPLEXES; DESIGN; ACID;
D O I：
10.1007/s10876-015-0950-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 3D metal coordination polymer (MCP), {[Zn-2(A mu(3)-OH)(btc)(bmip)]center dot H2O}(n) (1), where H(3)btc = 1,3,5-benzenetricarboxylate acid, bmip = 1,3-bis(2-methylimidazolyl)propane, was synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. Single crystal X-ray analysis revealed that MCP 1 features a 3D framework based on tetranuclear Zn(II) Clusters where the four zinc ions are coplanar, and shows an unusual binodal (3,10)-connected topology. Furthermore, the photoluminescent property of MCP 1 was investigated at room temperature. [GRAPHICS] .
引用
收藏
页码：573 / 582
页数：10
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