Synthesis, Structure and Luminescent Properties of Cd(II) Coordination Polymers Based on 4-Nitrobenzoic Acid and Bis(imidazol) Ligand

被引：0

作者：

Li Xiu-Mei ^{[1
]}

Wang Zhi-Tao ^{[1
]}

Pan Ya-Ru ^{[1
]}

机构：

[1] Tonghua Normal Univ, Fac Chem, Tonghua 134002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 04期

关键词：

4-nitrobenzoic acid; luminescence; coordination polymer; crystal structure; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ISOMERISM; COMPLEXES; BENZENEDICARBOXYLATE; MOLECULES; NETWORK; ZN(II); CO(II); PH;

D O I：

10.14102/j.cnki.0254-5861.2011-1803

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cd(II) coordination polymer, [Cd-0.5(nba)(bib)(0.5)](2n) (1, Hnba = 4-nitrobenzoic acid, bib = 1,4-bis(imidazol-1-yl)-butane), was synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions. Complex 1 belongs to the monoclinic system, C2/c space group, with a = 26.0600(14), b = 6.7889(4), c = 16.5825(9) angstrom,beta = 118.8120(10)degrees, V= 2570.6(2) angstrom(3), Z = 4. It shows one-dimensional chains and is further linked by pi-pi stacking interactions to yield a three-dimensional supramolecular structure. Thermal stability and luminescence of 1 were investigated.

引用

页码：653 / 658

页数：6

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