FeCl3: Highly Efficient Catalyst for Synthesis of α-Amino Nitriles

被引:12
作者
Heravi, Majid M. [1 ]
Ebrahimzadeh, Mojgan [1 ]
Oskooie, Hossein A. [1 ]
Baghernejad, Bita [1 ]
机构
[1] Alzahra Univ, Sch Sci, Dept Chem, Tehran, Iran
关键词
one-pot; FeCl3; trimethyl silyl cyanide; alpha-aminonitriles; ONE-POT SYNTHESIS; GREEN; ACID;
D O I
10.1002/cjoc.201090100
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
alpha-Amino nitriles are synthesized by the three-component coupling reaction of aldehydes, amines and trimethyl-silyl cyanide using FeCl3 as a solid acid catalyst, under solvent-free conditions in good yields. The catalyst was recovered by simple filtration and was recycled in subsequent reactions.
引用
收藏
页码:480 / 482
页数:3
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共 31 条
  • [1] Catalytic method for synthesis of aspirin by a green, efficient and recyclable solid acid catalyst (Preyssler's anion) at room temperature
    Bamoharram, Fatemeh F.
    Heravi, Majid M.
    Roshani, Mina
    Gharib, Ali
    Jahangir, Manouchehr
    [J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2007, 54 (04) : 1017 - 1020
  • [2] Preyssler catalyst,[NaP5W30O110]14- :: A green, efficient and reusable catalyst for esterification of salicylic acid with aliphatic and benzylic alcohols
    Bamoharram, FF
    Heravi, MM
    Roshani, M
    Jahangir, M
    Gharib, A
    [J]. APPLIED CATALYSIS A-GENERAL, 2006, 302 (01) : 42 - 47
  • [3] Iron-catalyzed reactions in organic synthesis
    Bolm, C
    Legros, J
    Le Paih, J
    Zani, L
    [J]. CHEMICAL REVIEWS, 2004, 104 (12) : 6217 - 6254
  • [4] DIASTEREOSELECTIVE STRECKER SYNTHESIS USING ALPHA-PHENYLGLYCINOL AS CHIRAL AUXILIARY
    CHAKRABORTY, TK
    REDDY, GV
    HUSSAIN, KA
    [J]. TETRAHEDRON LETTERS, 1991, 32 (51) : 7597 - 7600
  • [5] Vanadyl triflate as an efficient and recyclable catalyst for trimethylsilyl cyanide addition to carbonyl compounds
    De, SK
    Gibbs, RA
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 232 (1-2) : 123 - 125
  • [6] Bismuth trichloride catalyzed synthesis of α-aminonitriles
    De, SK
    Gibbs, RA
    [J]. TETRAHEDRON LETTERS, 2004, 45 (40) : 7407 - +
  • [7] Recent uses of iron (III) chloride in organic synthesis
    Díaz, DD
    Miranda, PO
    Padrón, JI
    Martín, VS
    [J]. CURRENT ORGANIC CHEMISTRY, 2006, 10 (04) : 457 - 476
  • [8] RECENT DEVELOPMENTS IN THE STEREOSELECTIVE SYNTHESIS OF ALPHA-AMINO-ACIDS
    DUTHALER, RO
    [J]. TETRAHEDRON, 1994, 50 (06) : 1539 - 1650
  • [9] Some recent applications of α-amino nitrile chemistry
    Enders, D
    Shilvock, JP
    [J]. CHEMICAL SOCIETY REVIEWS, 2000, 29 (05) : 359 - 373
  • [10] Advances in iron catalyzed cross coupling reactions
    Fürstner, A
    Martin, R
    [J]. CHEMISTRY LETTERS, 2005, 34 (05) : 624 - 629