Novel unsymmetrically π-elongated porphyrin for dye-sensitized TiO2 cells

被引:174
作者
Tanaka, Masanobu
Hayashi, Shinya
Eu, Seunghun
Umeyama, Tomokazu
Matano, Yoshihiro
Imahori, Hiroshi [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Int Innovat Ctr, Nishikyo Ku, Kyoto 6158520, Japan
关键词
D O I
10.1039/b702501g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel naphthyl-fused zinc porphyrin carboxylic acid has been synthesized and employed successfully in a dye-sensitized TiO2 solar cell, with a power conversion efficiency of 4.1%, which is improved by 50% relative to the unfused porphyrin reference cell.
引用
收藏
页码:2069 / 2071
页数:3
相关论文
共 29 条
[1]   Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like TiO2 nanowires made by the "oriented attachment" mechanism [J].
Adachi, M ;
Murata, Y ;
Takao, J ;
Jiu, JT ;
Sakamoto, M ;
Wang, FM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) :14943-14949
[2]   Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].
Anderson, HL .
CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330
[3]   CONJUGATED PORPHYRIN LADDERS [J].
ANDERSON, HL .
INORGANIC CHEMISTRY, 1994, 33 (05) :972-981
[4]   Electron trapping in porphyrin-sensitized porous nanocrystalline TiO2 electrodes [J].
Boschloo, GK ;
Goossens, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (50) :19489-19494
[5]   Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin [J].
Cammidge, AN ;
Scaife, PJ ;
Berber, G ;
Hughes, DL .
ORGANIC LETTERS, 2005, 7 (16) :3413-3416
[6]   A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells [J].
Chen, Chia-Yuan ;
Wu, Shi-Jhang ;
Wu, Chun-Guey ;
Chen, Jian-Ging ;
Ho, Kuo-Chuan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5822-5825
[7]   Adsorption and photoactivity of tetra(4-carboxyphenyl)porphyrin (TCPP) on nanoparticulate TiO2 [J].
Cherian, S ;
Wamser, CC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (15) :3624-3629
[8]   Conversion efficiency of 10.8% by a dye-sensitized solar cell using a TiO2 electrode with high haze [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
APPLIED PHYSICS LETTERS, 2006, 88 (22)
[9]   STUDY OF THE EFFECTS OF SUBSTITUTION ON THE ABSORPTION SPECTRA OF PORPHIN [J].
GOUTERMAN, M .
JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (05) :1139-1161
[10]   SPECTRA OF PORPHYRINS [J].
GOUTERMAN, M .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1961, 6 (01) :138-&