Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO4

被引：47

作者：

Xia, Qineng ^{[1
,2
]}

Zhuang, Xiaojing ^{[2
]}

Li, Molly Meng-Jung ^{[1
]}

Peng, Yung-Kang ^{[1
]}

Liu, Guoliang ^{[1
]}

Wu, Tai-Sing ^{[3
]}

Soo, Yun-Liang ^{[3
]}

Gong, Xue-Qing ^{[2
]}

Wang, Yanqin ^{[2
]}

Tsang, Shik Chi Edman ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Wolfson Catalysis Ctr, Oxford OX1 3QR, England

[2] E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

[3] Natl Tsing Hua Univ, Dept Phys, Hsinchu, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 29期

关键词：

FUEL PRODUCTION; OXYGEN DEFECTS; P-31; NMR; ACID; TRANSESTERIFICATION; DEOXYGENATION; PERFORMANCE; OXIDES;

D O I：

10.1039/c5cc10419j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Near quantitative carbon yields of diesel-range alkanes were achieved from the hydrodeoxygenation of triglycerides over Pd/NbOPO4 under mild conditions with no catalyst deactivation: catalyst characterization and theoretical calculations suggest that the high hydrodeoxygenation activity originated from the synergistic effect of Pd and strong Lewis acidity on the unique structure of NbOPO4.

引用

页码：5160 / 5163

页数：4

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