Intramolecular Diels Alder reactions in highly organized imidazolium salt-based ionic liquid crystals

被引：20

作者：

Do, Tien Dat ^{[1
]}

Schmitzer, Andreea R. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

RSC ADVANCES | 2015年 / 5卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SELECTIVITY; BROMIDES; SOLVENTS;

D O I：

10.1039/c4ra11693c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes the development of a new family of ionic liquid crystals based on imidazolium salts and their applications as media for intramolecular Diels Alder reactions. The use of highly organized smectic T phases was shown to be an efficient method to obtain the intramolecular Diels Alder product in high yields, without using high dilution conditions. The ionic liquid crystal media can be recycled in an easy procedure and reused up to at least five times, without loss of reactivity and selectivity.

引用

页码：635 / 639

页数：5

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