Synthesis and Optical Characterization of Terbium Doped M2SiO4 Nanophosphors

被引:8
作者
Singh, Devender [1 ,2 ]
Tanwar, Vijeta [1 ]
Bhagwan, Shri [1 ]
Simantilleke, Anura Priyajith [2 ]
Singh, Ishwar [1 ]
Kadyan, Pratap Singh [1 ]
机构
[1] Maharshi Dayanand Univ, Dept Chem, Rohtak 124001, Haryana, India
[2] Univ Minho, Ctr Fis, P-4710057 Braga, Portugal
关键词
Sol-Gel Method; Green Phosphor; Tb3+; Luminescent Properties; SOL-GEL SYNTHESIS; LUMINESCENCE; PHOTOLUMINESCENCE; IONS; SIO2; TB;
D O I
10.1166/asl.2014.5522
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
M2SiO4 [M = Mg, Ca, Sr] doped with Tb3+ nanophosphors were synthesized with sol gel technology. Crystal structure and their luminescent properties were analyzed by X-ray diffraction and spectrofluorimeter. Under the irradiation of 225 nm ultraviolet light, the spectra of prepared phosphors exhibited emission at 543 nm attributed to the magnetic dipole transition (D-5(4) -> F-7(5)) of the Tb3+ Photo luminescent properties of M2SiO4:Tb3+ nanophosphors were also studied as a function of dopant and effect of heating. Transmission electron microscopy (TEM) studies were carried out to explore the morphological features of the phosphors.
引用
收藏
页码:1531 / 1534
页数:4
相关论文
共 14 条
[1]   Room-temperature photoluminescence from Tb ions implanted in SiO2 on Si [J].
Amekura, H ;
Eckau, A ;
Carius, R ;
Buchal, C .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (07) :3867-3871
[2]   LUMINESCENCE OF EU3+ IONS DURING THERMAL DENSIFICATION OF SIO2 GEL [J].
CAMPOSTRINI, R ;
CARTURAN, G ;
FERRARI, M ;
MONTAGNA, M ;
PILLA, O .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (03) :745-753
[3]   Excitons in Si nanocrystals:: Confinement and migration effects -: art. no. 195309 [J].
Heitmann, J ;
Müller, F ;
Yi, LX ;
Zacharias, M ;
Kovalev, D ;
Eichhorn, F .
PHYSICAL REVIEW B, 2004, 69 (19) :195309-1
[4]   Luminescence of nanophoshors LU2SiO5doped with different concentration of Tb3+ by in situ composition of hybrid precursors [J].
Huang, HH ;
Yan, B .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 117 (03) :261-264
[5]   Matrix-inducing synthesis and luminescence of novel unexpected coral-like morphology Mg2Gd8(SiO4)6O2:Tb3+ nanophosphor from in situ composing multicomponent hybrid precursors [J].
Huang, HH ;
Yan, B .
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (07) :919-922
[6]   Sol-gel synthesis and green luminescence of nanocrystalline Zn2SiO4:Mn phosphor [J].
Kwon, MS ;
Kim, CJ ;
Park, HL ;
Kim, TW ;
Lee, HS .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (15) :4089-4091
[7]   Size-dependent elastic modulus of Cu and Au thin films [J].
Liang, LH ;
Li, JC ;
Jiang, Q .
SOLID STATE COMMUNICATIONS, 2002, 121 (08) :453-455
[8]   Correlated structural and optical investigation of terbium-doped zinc oxide nanocrystals [J].
Liu, SM ;
Liu, FQ ;
Guo, HQ ;
Zhang, ZH ;
Wang, ZG .
PHYSICS LETTERS A, 2000, 271 (1-2) :128-133
[9]   LUMINESCENCE BEHAVIOR OF EUROPIUM COMPLEXES IN SOL-GEL DERIVED HOST MATERIALS [J].
MATTHEWS, LR ;
KNOBBE, ET .
CHEMISTRY OF MATERIALS, 1993, 5 (12) :1697-1700
[10]   Synthesis of SrAl2O4:Eu, Dy phosphor nanometer powders by sol-gel processes and its optical properties [J].
Peng, TY ;
Huajun, L ;
Yang, HP ;
Yan, CH .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 85 (01) :68-72