The water-hydroxyl radical complex:: A matrix isolation study

被引：73

作者：

Engdahl, A ^{[1
]}

Karlström, G ^{[1
]}

Nelander, B ^{[1
]}

机构：

[1] Lund Univ, Ctr Chem, S-22100 Lund, Sweden

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 118卷 / 17期

关键词：

D O I：

10.1063/1.1563608

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The water-hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O-O axis in the matrix. (C) 2003 American Institute of Physics.

引用

页码：7797 / 7802

页数：6

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