Metal-containing polymers synthesized via acyclic diene metathesis (ADMET) polymerization using electrochemically-reduced tungsten-based catalyst:: Polycarbosilanes

被引：14

作者：

Karabulut, Solmaz ^{[1
]}

Aydogdu, Cemil ^{[1
]}

Duz, Bulent ^{[1
]}

Imamoglu, Yavuz ^{[1
]}

机构：

[1] Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2007年 / 17卷 / 03期

关键词：

silicon-containing polymers; ADMET polymerization; electrochemistry; catalysis; WCl6;

D O I：

10.1007/s10904-007-9141-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Acyclic diene metathesis (ADMET) polymerization of dienes containing silicon using electrochemically produced active catalyst species (WCl6-e(-) -Al-CH2Cl2) was investigated. Silicon-containing unsaturated polymers were characterized by H-1- and C-13-NMR spectroscopy, gel permeation chromatography (GPC) and elemental analysis. The thermal behavior of the polymers was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

引用

页码：517 / 523

页数：7

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