Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster

被引：83

作者：

Noro, Shin-ichiro ^{[1
]}

Tsunashima, Ryo ^{[1
]}

Kamiya, Yuichi ^{[3
]}

Uemura, Kazuhiro ^{[4
]}

Kita, Hidetoshi ^{[4
]}

Cronin, Leroy ^{[2
]}

Akutagawa, Tomoyuki ^{[1
]}

Nakamura, Takayoshi ^{[1
]}

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0010020, Japan

[2] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[3] Hokkaido Univ, Res Fac Environm Earth Sci, Sapporo, Hokkaido 0600812, Japan

[4] Yamaguchi Univ, Grad Sch Sci & Engn, Yamaguchi 7558611, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 46期

关键词：

adsorption; heterogeneous catalysis; microporous materials; organic-inorganic hybrid composites; polyoxometalates; TOLERANT SOLID ACID; MOLYBDENUM-BLUE; Y ZEOLITE; SURFACE; WATER; LANGMUIR; DESIGN; CS2.5H0.5PW12O40; ASSEMBLIES; COMPLEXES;

D O I：

10.1002/anie.200903142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functional inner space: A gigantic ringshaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme). © 2009 Wiley-VCH Verlag GmbH &. Co. KCaA.

引用

页码：8703 / 8706

页数：4

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