Cyclohexane oxidation using advanced oxidation processes with metals and metal oxides as catalysts: a review

Selective oxidation of cyclohexane has gained substantial interest in the field of research due to the prominence of its products in industrial processes. Particularly, advanced oxidation processes (AOPs) constitute a positive technology for the oxidation of cyclohexane owing to their high oxidation potentials and environmental benign properties. This review entails to address the progress made in advanced oxidation of cyclohexane over nanostructured metals and metal oxides catalysts. The main focus is directed toward the photocatalysis, Fenton oxidation and ozonation as advanced oxidation processes. Mainly, the fundamental principles, prime factors of the AOPs in conjunction with metal and metal oxide catalysts and the mechanistic insight toward the oxidation of cyclohexane are highlighted. The affirmative effects of the metals and metal oxide catalysts mainly focusing on particle size, structure and elemental composition is stressed. Lastly, the advantages and disadvantages of the AOPs and the strategic approaches to counter the disadvantages are also clearly elucidated.