Synthesis and characterization of Ru(II) arene complexes, [Ru(η6-arene)(dppm)H]+ (η6-arene=benzene, p-cymene or hexamethylbenzene), [Ru(η6-arene)(py)3]2+ and [Ru(η6-arene)(py)2Cl]+

被引：0
|
作者：
Sisodiya, OS [1 ]
Sahay, AN [1 ]
Pandey, DS [1 ]
机构：
[1] APS Univ, Dept Chem, Rewa 486003, Madhya Pradesh, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2000年 / 39卷 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of [{Ru(eta (6)-arene)Cl-2}(2)] (eta (6)-arene=benzene. p-cymene, hexamethylbenzene) in methanol, in presence of AgBF4/AgPF6 with 1,2-bis(diphenylphosphino)methane (dppm) give cationic hydride complexes [Ru(eta (6)-arene)(dppm)H](+). However, under similar and some changed conditions, reaction with pyridine result in the formation of [Ru(eta (6)-arene)(py)(3)](2+) and [Ru(eta (6)-arene)(py)(2)Cl](+). The reaction products have been characterized by elemental analyses, IR, H-1, P-31 NMR and FAB mass spectra.
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页码：453 / 456
页数：4
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