Reduced Graphene Oxide for Room Temperature Ammonia (NH3) Gas Sensor

被引:23
作者
Li, Weiwei [1 ,2 ]
Li, Xian [2 ,3 ]
Cai, Li [1 ]
Sun, Yilin [2 ]
Sun, Mengxing [2 ]
Xie, Dan [2 ]
机构
[1] Air Force Engn Univ, Dept Fdn, Xian 710051, Shaanxi, Peoples R China
[2] Tsinghua Univ, Inst Microelect, Tsinghua Natl Lab Informat Sci & Technol TNList, Beijing 100084, Peoples R China
[3] Chinese Acad Agr Sci, Agr Informat Inst, Minist Agr, Key Lab Agr Informat Serv Technol, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Reduced Graphene Oxide; Ammonia; Gas Sensors; Room Temperature; SENSING PERFORMANCE; FILM; RGO;
D O I
10.1166/jnn.2018.15563
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reduced graphene oxide (rGO) has attracted an enormous interest as a promising candidate material for gas detection due to its unique atomic structure. In the present work, rGO films were fabricated by the layer-by-layer (LBL) self-assembly and thermal reduction method for detecting ammonia (NH3) gas at room temperature. The single-and multi-layer rGO films exhibited high sensitivity and fast sensing performance to 5-50 ppm NH3, among which bi-layer rGO film showed the best sensitivity, recovery and the shortest response/recovery time to different concentrations of NH3. For bi-layer rGO film, the shortest response time to 50 ppm NH3 was 24 s and the recovery rate to 5 ppm NH3 was 98%, respectively. The sensing mechanism is attributed to the thinner rGO films and a larger specific surface area offered by the LBL self-assembly.
引用
收藏
页码:7927 / 7932
页数:6
相关论文
共 31 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Highly sensitive NO2 gas sensor based on ozone treated graphene [J].
Chung, Min Gyun ;
Kim, Dai Hong ;
Lee, Hyun Myoung ;
Kim, Taewoo ;
Choi, Jong Ho ;
Seo, Dong Kyun ;
Yoo, Ji-Beom ;
Hong, Seong-Hyeon ;
Kang, Tae June ;
Kim, Yong Hyup .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 166 :172-176
[3]   Gas sensor based on p-phenylenediamine reduced graphene oxide [J].
Hu, Nantao ;
Wang, Yanyan ;
Chai, Jing ;
Gao, Rungang ;
Yang, Zhi ;
Kong, Eric Siu-Wai ;
Zhang, Yafei .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 163 (01) :107-114
[4]   Improvement of Gas-Sensing Performance of Large-Area Tungsten Disulfide Nanosheets by Surface Functionalization [J].
Ko, Kyung Yong ;
Song, Jeong-Gyu ;
Kim, Youngjun ;
Choi, Taejin ;
Shin, Sera ;
Lee, Chang Wan ;
Lee, Kyounghoon ;
Koo, Jahyun ;
Lee, Hoonkyung ;
Kim, Jongbaeg ;
Lee, Taeyoon ;
Park, Jusang ;
Kim, Hyungjun .
ACS NANO, 2016, 10 (10) :9287-9296
[5]   Heterogeneous Sensitization of Metal-Organic Framework Driven Metal@Metal Oxide Complex Catalysts on an Oxide Nanofiber Scaffold Toward Superior Gas Sensors [J].
Koo, Won-Tae ;
Choi, Seon-Jin ;
Kim, Sang-Joon ;
Jang, Ji-Soo ;
Tuller, Harry L. ;
Kim, Il-Doo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (40) :13431-13437
[6]   Adsorption of H2O, NH3, CO, NO2, and NO on graphene:: A first-principles study [J].
Leenaerts, O. ;
Partoens, B. ;
Peeters, F. M. .
PHYSICAL REVIEW B, 2008, 77 (12)
[7]   Reduced graphene oxide (rGO) decorated TiO2 microspheres for selective room-temperature gas sensors [J].
Li, Xiaogan ;
Zhao, Yangyang ;
Wang, Xueyan ;
Wang, Jing ;
Gaskov, Alexander M. ;
Akbar, S. A. .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 230 :330-336
[8]   Toward Practical Gas Sensing with Highly Reduced Graphene Oxide: A New Signal Processing Method To Circumvent Run-to-Run and Device-to-Device Variations [J].
Lu, Ganhua ;
Park, Sungjin ;
Yu, Kehan ;
Ruoff, Rodney S. ;
Ocola, Leonidas E. ;
Rosenmann, Daniel ;
Chen, Junhong .
ACS NANO, 2011, 5 (02) :1154-1164
[9]   Reduced graphene oxide for room-temperature gas sensors [J].
Lu, Ganhua ;
Ocola, Leonidas E. ;
Chen, Junhong .
NANOTECHNOLOGY, 2009, 20 (44)
[10]   Tuning gas-sensing properties of reduced graphene oxide using tin oxide nanocrystals [J].
Mao, Shun ;
Cui, Shumao ;
Lu, Ganhua ;
Yu, Kehan ;
Wen, Zhenhai ;
Chen, Junhong .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (22) :11009-11013