Synthesis of magnetic nanoporous carbon from metal-organic framework for the fast removal of organic dye from aqueous solution

被引:62
作者
Jiao, Caina [1 ]
Wang, Yanen [1 ]
Li, Menghua [1 ]
Wu, Qiuhua [1 ]
Wang, Chun [1 ]
Wang, Zhi [1 ]
机构
[1] Agr Univ Hebei, Coll Sci, Baoding 071001, Peoples R China
基金
中国国家自然科学基金;
关键词
Magnetic nanoporous carbon; Metal organic framework; Adsorption; Dye; HIERARCHICALLY POROUS CARBON; METHYLENE-BLUE; NANOPARTICLES; ADSORPTION; ADSORBENT; GRAPHENE; POROSITY; MICROEXTRACTION; FABRICATION; POLLUTANTS;
D O I
10.1016/j.jmmm.2016.01.031
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, a magnetic nanoporous carbon (Fe3O4/NPC) was successfully synthesized by using MOF-5 as carbon precursor and Fe salt as magnetic precursor. The texture properties of the as-synthesized nanocomposite were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), vibration sample magnetometer (VSM), and N-2 adsorption-desorption isotherms. The Fe3O4/NPC had a high surface area with strong magnetic strength. Its adsorption behavior was tested by its adsorption capacity for the removal of methylene blue from aqueous solution. The results demonstrated that the Fe3O4/NPC had a high adsorption capacity, rapid adsorption rate, and easy magnetic separabilty. Moreover, the adsorbent could be easily regenerated by washing it with ethanol. The Fe3O4/NPC can be used as a good alternative for the effective removal of organic dyes from wastewater. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:24 / 30
页数:7
相关论文
共 36 条
[1]   Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite [J].
Ai, Lunhong ;
Zhang, Chunying ;
Chen, Zhonglan .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 192 (03) :1515-1524
[2]   A new family of carbon materials: synthesis of MOF-derived nanoporous carbons and their promising applications [J].
Chaikittisilp, Watcharop ;
Ariga, Katsuhiko ;
Yamauchi, Yusuke .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (01) :14-19
[3]   Preparation of carbon microspheres decorated with silver nanoparticles and their ability to remove dyes from aqueous solution [J].
Chen, Qingchun ;
Wu, Qingsheng .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 283 :193-201
[4]   Highly efficient decomposition of organic dyes by aqueous-fiber phase transfer and in situ catalytic oxidation, using fiber-supported cobalt phthalocyanine [J].
Chen, Wenxing ;
Lu, Wangyang ;
Yao, Yuyuan ;
Xu, Minhong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (17) :6240-6245
[5]   Comprehensive study of mesoporous carbon functionalized with carboxylate groups and magnetic nanoparticles as a promising adsorbent [J].
Chi, Yue ;
Geng, Wangchang ;
Zhao, Liang ;
Yan, Xiao ;
Yuan, Qing ;
Li, Nan ;
Li, Xiaotian .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 369 :366-372
[6]   Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5750-5765
[7]   New photocatalysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye [J].
Du, Jing-Jing ;
Yuan, Yu-Peng ;
Sun, Jia-Xin ;
Peng, Fu-Min ;
Jiang, Xia ;
Qiu, Ling-Guang ;
Xie, An-Jian ;
Shen, Yu-Hua ;
Zhu, Jun-Fa .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 190 (1-3) :945-951
[8]   Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? [J].
Farha, Omar K. ;
Eryazici, Ibrahim ;
Jeong, Nak Cheon ;
Hauser, Brad G. ;
Wilmer, Christopher E. ;
Sarjeant, Amy A. ;
Snurr, Randall Q. ;
Nguyen, SonBinh T. ;
Yazaydin, A. Oezguer ;
Hupp, Joseph T. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :15016-15021
[9]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
[10]   Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235) [J].
Haque, Enamul ;
Jun, Jong Won ;
Jhung, Sung Hwa .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 185 (01) :507-511