Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

被引：70
作者：
Kong, Weiguang [1 ]
An, Hejun [1 ]
Song, Qiuling [1 ]
机构：
[1] Huaqiao Univ, Coll Mat Sci & Engn, Coll Chem Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 64期
关键词：
ALIPHATIC CARBOXYLIC-ACIDS; CARBON MULTIPLE BONDS; PHOTOREDOX CATALYSIS; UNACTIVATED ALKENES; DIASTEREOSELECTIVE SYNTHESIS; TRIFLUOROMETHYLATION REACTIONS; VICINAL DIFUNCTIONALIZATION; ORGANIC-SYNTHESIS; ELECTRON-TRANSFER; HIGHLY EFFICIENT;
D O I：
10.1039/c7cc03520a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unconventional reductive quenching cycle was developed to realize the visible-light-induced thiotrifluoromethylation of terminal alkenes. CF(3)SO(2)Nawas used as an easy tohandleCF(3) radical source to afford the desired products in moderate to good yields. Mild reaction conditions and a broad substrate scope feature in this transformation.
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收藏
页码：8968 / 8971
页数：4
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