Cross-Linked Chitosan as a Polymer Network Binder for an Antimony Anode in Sodium-Ion Batteries

被引:90
作者
Gao, Hongcai [1 ]
Zhou, Weidong [1 ]
Jang, Ji-Hoon [1 ]
Goodenough, John B. [1 ]
机构
[1] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
antimony; cross-linking; energy storage; polymer networks; sodium-ion batteries; SOLID-ELECTROLYTE INTERPHASE; PERFORMANCE SILICON ANODES; LI-ION; NEGATIVE ELECTRODES; HIGH-CAPACITY; HOLLOW NANOSPHERES; ENERGY-STORAGE; NA; SB; SPECTROSCOPY;
D O I
10.1002/aenm.201502130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A polymer network from a cross-linking chemistry between chitosan and glutaraldehyde is designed for a high performance antimony anode in sodium-ion batteries. The polymer network can mitigate efficiently the volume change of antimony anode upon sodiation/desodiation, leading to excellent cycling stability and high Coulombic efficiency. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页数:7
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