Effect of sinter temperature on the electrical properties of TiO2-based capacitor-varistors

被引:59
作者
Li, CP [1 ]
Wang, JF [1 ]
Su, WB [1 ]
Chen, HC [1 ]
Wang, YJ [1 ]
Zhuang, DX [1 ]
机构
[1] Shandong Univ, Dept Phys, Jinan 250100, Peoples R China
关键词
varistors; sintering temperature; titania oxide; yttrium; oxide; barriers; electrical properties;
D O I
10.1016/S0167-577X(02)00996-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of sinter temperature on the electrical properties of a new TiO2-based varistor system, TiO2.Y2O3.Nb2O5, was investigated by measuring the properties of I-V permittivity and grain-boundary barriers. The varistor of 99.30%TiO2.0.60%Y2O3.0.10%Nb2O5 composite sintered at 1400 degreesC has a maximal nonlinear coefficient of a alpha = 7.8, a low reference electrical field of 12.8 V-mm-at I mA cm(-2), a high density of 4.20 g/cm(3) and the ultrahigh permittivity of more than 85 000 (measured at I kHz), which is consistent with its highest and narrowest grain-boundary barriers. Due to these properties the (Nb, Y)-doped TiO2 varistors sintered at 1400 degreesC has varistor-capacitance multifunctional components, which are quite useful in the situation that the voltage protection and high-frequency noise absorption are meanwhile required. In order to illustrate the grain-boundary barrier formation in TiO2.Y2O3.Nb2O5 varistors, a grain-boundary defect barrier model was also introduced. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1400 / 1405
页数:6
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