Wholly biomass derivable sustainable polymers by ring-opening metathesis polymerisation of monomers obtained from furfuryl alcohol and itaconic anhydride

被引：22

作者：

Bai, Yinjuan ^{[1
,2
]}

Clark, James H. ^{[1
]}

Farmer, Thomas J. ^{[1
]}

Ingram, Ian D. V. ^{[1
]}

North, Michael ^{[1
]}

机构：

[1] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England

[2] Northwest Univ, Dept Chem, Xian, Shaanxi, Peoples R China

来源：

POLYMER CHEMISTRY | 2017年 / 8卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

UNSATURATED POLYESTER RESINS; LIGNOCELLULOSIC BIOMASS; PLATFORM MOLECULES; MALEIC-ANHYDRIDE; ACID; CATALYSTS; HYDROGENATION; ITACONATE)S; CHEMICALS; ESTERS;

D O I：

10.1039/c7py00486a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ring-opening metathesis polymerisation (ROMP) of oxanorbornene esters by Grubbs second generation catalyst is used to prepare a range of wholly biomass-derivable homo and copolymers. Eight ester monomers are prepared by esterification of the corresponding carboxylic acid which itself is formed by a 100% atom-economical tandem Diels-Alder-lactonisation reaction of itaconic anhydride and furfuryl alcohol. The well-controlled nature of the ROMP is confirmed by NMR spectroscopy studies and facilitated the preparation of homopolymers, random copolymers and block copolymers with good control over the polymer molecular weight and molecular weight distribution.

引用

页码：3074 / 3081

页数：8

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