Wholly biomass derivable sustainable polymers by ring-opening metathesis polymerisation of monomers obtained from furfuryl alcohol and itaconic anhydride

被引：22

作者：

Bai, Yinjuan ^{[1
,2
]}

Clark, James H. ^{[1
]}

Farmer, Thomas J. ^{[1
]}

Ingram, Ian D. V. ^{[1
]}

North, Michael ^{[1
]}

机构：

[1] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England

[2] Northwest Univ, Dept Chem, Xian, Shaanxi, Peoples R China

来源：

POLYMER CHEMISTRY | 2017年 / 8卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

UNSATURATED POLYESTER RESINS; LIGNOCELLULOSIC BIOMASS; PLATFORM MOLECULES; MALEIC-ANHYDRIDE; ACID; CATALYSTS; HYDROGENATION; ITACONATE)S; CHEMICALS; ESTERS;

D O I：

10.1039/c7py00486a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ring-opening metathesis polymerisation (ROMP) of oxanorbornene esters by Grubbs second generation catalyst is used to prepare a range of wholly biomass-derivable homo and copolymers. Eight ester monomers are prepared by esterification of the corresponding carboxylic acid which itself is formed by a 100% atom-economical tandem Diels-Alder-lactonisation reaction of itaconic anhydride and furfuryl alcohol. The well-controlled nature of the ROMP is confirmed by NMR spectroscopy studies and facilitated the preparation of homopolymers, random copolymers and block copolymers with good control over the polymer molecular weight and molecular weight distribution.

引用

页码：3074 / 3081

页数：8

共 37 条

[1] Solvent effects on Grubbs' pre-catalyst initiation rates [J].

Ashworth, Ian W. ;

Nelson, David J. ;

Percy, Jonathan M. .

DALTON TRANSACTIONS, 2013, 42 (12) :4110-4113

[2] Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcohol [J].

Bai, Yinjuan ;

De Bruyn, Mario ;

Clark, James H. ;

Dodson, Jennifer R. ;

Farmer, Thomas J. ;

Honore, Mathilde ;

Ingram, Ian D. V. ;

Naguib, Mohamed ;

Whitwood, Adrian C. ;

North, Michael .

GREEN CHEMISTRY, 2016, 18 (14) :3945-3948

[3]

Berovic M, 2007, BIOTECHNOL ANN REV, V13, P303, DOI 10.1016/S1387-2656(07)13011-8

[4] Living ring-opening metathesis polymerisation of amino ester functionalised norbornenes [J].

Biagini, SCG ;

Coles, MP ;

Gibson, VC ;

Giles, MR ;

Marshall, EL ;

North, M .

POLYMER, 1998, 39 (05) :1007-1014

[5] Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water [J].

Chen, Xiufang ;

Zhang, Ligang ;

Zhang, Bo ;

Guo, Xingcui ;

Mu, Xindong .

SCIENTIFIC REPORTS, 2016, 6

[6]

Crowell J. H., 1939, US Patent US, Patent No. [2258947A, 2258947]

[7]

Dutta S, 2015, GREEN CHEM, V17, P3737, DOI [10.1039/C5GC00936G, 10.1039/c5gc00936g]

[8] Post-polymerisation modification of bio-derived unsaturated polyester resins via Michael additions of 1,3-dicarbonyls [J].

Farmer, T. J. ;

Clark, J. H. ;

Macquarrie, D. J. ;

Ogunjobi, J. K. ;

Castle, R. L. .

POLYMER CHEMISTRY, 2016, 7 (08) :1650-1658

[9]

Farmer T. J., 2015, INTRO CHEM BIOMASS, DOI DOI 10.1002/9781118714478.CH4

[10] Synthesis of Unsaturated Polyester Resins from Various Bio-Derived Platform Molecules [J].

Farmer, Thomas J. ;

Castle, Rachael L. ;

Clark, James H. ;

Macquarrie, Duncan J. .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2015, 16 (07) :14912-14932

← 1 2 3 4 →