[μ-2-Methyl-5-(methylsulfanylmethyl)azaferrocene]bis(pentacarbonyltungsten)

被引：3
|
作者：
Kowalski, Konrad
White, Andrew J. P.
机构：
[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW 7AZ, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536806056121
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [W2Fe(C5H5)(C7H10NS)(CO)(10)], was prepared by reaction of 5-methylsulfanylmethyl-2-methyl azaferrocene with photochemically generated [W(CO)(5)].THF. THF. The X-ray structural analysis showed the azaferrocenyl unit to have adopted a nearly eclipsed geometry. The geometries at the two tungsten centers are distorted octahedral.
引用
收藏
页码：M392 / M393
页数：2
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