Mono- and di-t-butyl substituted 2,2′-bis(1,3-dithia[3]ferrocenophane-2-ylidene) derivatives:: TTF-like ferrocene analogs

被引：2

作者：

Sato, Masaru ^{[1
]}

Miyagawa, Yuta ^{[1
]}

Okada, Shizuka ^{[1
]}

Saito, Noboru ^{[1
]}

机构：

[1] Saitama Univ, Fac Sci, Dept Chem, Urawa, Saitama 3388570, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 14期

关键词：

ferrocene; tetrathioethene derivative; redox behavior; electron interaction;

D O I：

10.1016/j.jorganchem.2007.02.045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono- and di-t-butyl substituted 2,2'-bis(1,3-dithia[3]ferrocenophane-2-ylidene) derivatives were prepared. These derivatives showed the E-1/2(1) in lower potential region than that of differrocenyl-ethene and -ethyne. Also, the Delta E-1/2 value declined according to the increase of a t-butyl group. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：3089 / 3093

页数：5

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