Acentric and Centric interpenetrations of an Anionic Framework Mediated by Cation Sizes: The Alkali-Metal Tin(II) Benzenedicarboxylates A2Sn2(bdc)3(H2O)x (A = Li, Na, K, Rh, Cs)

被引：35

作者：

Wang, Xiqu ^{[1
]}

Liu, Lumei ^{[1
]}

Makarenko, Tatyana ^{[1
]}

Jacobson, Allan J. ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 04期

关键词：

CHEMISTRY; DESIGN; BDC;

D O I：

10.1021/cg100049s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of alkali-metal tin benzenedicarboxylates A(2)Sn(2)(bdc)(3)(H2O), A = Li, Na, K, Rb, Cs, in single crystal Forms have been synthesized by using a hydrothermal technique. The compounds all have cubic crystal structures based on a very open anionic [Sn-2(bdc)(3)](2) framework which is 8-fold interpenetrated noncentrosymmetrically (space group I23) in Li2Sn2(bdc)3(H2O2), 1, K2Sn2(bdc)(3), 3, Rb2Sn2(bdc)(3), 4, and Cs,Sn,(bdc)(3), 5, but centrosymmetrically (space group Pr/3) in Na7Sn,(bdc)(3)(H2O), 2. The ion size and coordination requirements of the alkali ions play an important role in the interpenetration of the anionic framework and the symmetry of the structures.

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页码：1960 / 1965

页数：6

相关论文

共 21 条

[1] In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure [J].

Anokhina, EV ;

Vougo-Zanda, M ;

Wang, XQ ;

Jacobson, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :15000-15001

[2] Tin(II) oxalates synthesized in the presence of structure-directing organic amines: Members of a potentially vast class of new open-framework and related materials [J].

Ayyappan, S ;

Cheetham, AK ;

Natarajan, S ;

Rao, CNR .

CHEMISTRY OF MATERIALS, 1998, 10 (11) :3746-3755

[3] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[4]

DEWAN JC, 1977, DALTON T, P368

[5] SLOWDOWN OR CRISIS - EDITORIAL INTRODUCTION [J].

EVANS, D ;

KAPLINSKY, R .

IDS BULLETIN-INSTITUTE OF DEVELOPMENT STUDIES, 1985, 16 (01) :1-8

[6] Physical chemistry -: Trapped gas [J].

Férey, G .

NATURE, 2005, 436 (7048) :187-188

[7] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[8] DIALKYLTIN DERIVATIVES OF DICARBOXYLIC-ACIDS - SYNTHESIS, CHARACTERIZATION AND INVITRO ANTITUMOR PROPERTIES [J].

GIELEN, M ;

BOUALAM, M ;

MERIEM, A ;

MAHIEU, B ;

BIESEMANS, M ;

WILLEM, R .

HETEROATOM CHEMISTRY, 1992, 3 (04) :449-452

[9] Influence of the reaction temperature and pH on the coordination modes of the 1,4-benzenedicarboxylate (BDC) ligand:: A case study of the NiII(BDC)/2,2′-bipyridine system [J].

Go, YB ;

Wang, XQ ;

Anokhina, EV ;

Jacobson, AJ .

INORGANIC CHEMISTRY, 2005, 44 (23) :8265-8271

[10] Aromatic inclusion within a neutral cavity-containing rectangular grid [J].

Groeneman, RH ;

MacGillivray, LR ;

Atwood, JL .

CHEMICAL COMMUNICATIONS, 1998, (24) :2735-2736