Facile hydrolysis synthesis of novel Bi4O5Br2 photocatalyst with enhanced visible light photocatalytic activity for the degradation of resorcinol

被引:42
作者
Mao, Xiaoming [1 ,2 ]
Xie, Fangxia [2 ]
Li, Min [1 ]
机构
[1] Changzhi Univ, Dept Chem, Changzhi 046011, Peoples R China
[2] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China
基金
中国国家自然科学基金;
关键词
Novel Bi4O5Br2 photocatalyst; Nanoparticles; Semiconductors; Resorcinol; Visible light photocatalysis; PERFORMANCE;
D O I
10.1016/j.matlet.2015.12.090
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel Bi4O5Br2 nanoparticle photocatalyst had been synthesized successfully through a facile, one-step, and energy-saving hydrolysis route. The band gap energy of as-prepared Bi4O5Br2 semiconductor was 2.0 eV, obviously lower than that of BiOBr. This can be attributed to the adjustment of the valence band maximum. The as-prepared Bi4O5Br2 could efficiently degrade resorcinol under visible light irradiation, and exhibited an enhanced visible light driven photocatalytic activity compared to BiOBr photocatalyst. The photocatalytic activity of Bi4O5Br2 was appropriately 31 times than that of BiOBr sample. In addition, the as-prepared Bi4O5Br2 sample possessed relatively high chemical stability, and this feature will benefit its practical application for the treatment of other organic pollutants. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:296 / 299
页数:4
相关论文
共 12 条
[1]   The dominant {001} facet-dependent enhanced visible-light photoactivity of ultrathin BiOBr nanosheets [J].
Chen, Jing ;
Guan, Meili ;
Cai, Weizheng ;
Guo, Jinju ;
Xiao, Chong ;
Zhang, Gaoke .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (38) :20909-20914
[2]   Graphene/semiconductor nanocomposites (GSNs) for heterogeneous photocatalytic decolorization of wastewaters contaminated with synthetic dyes: A review [J].
Chowdhury, Shamik ;
Balasubramanian, Rajasekhar .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 160 :307-324
[3]   Controlled hydrothermal synthesis of bismuth oxyhalide nanobelts and nanotubes [J].
Deng, H ;
Wang, JW ;
Peng, Q ;
Wang, X ;
Li, YD .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (22) :6519-6524
[4]   Synthesis of BiOBr, Bi3O4Br, and Bi12O17Br2 by controlled hydrothermal method and their photocatalytic properties [J].
Li, Kun-Lin ;
Lee, Wenlian William ;
Lu, Chung-Shin ;
Dai, Yong-Ming ;
Chou, Shang-Yi ;
Chen, Hong-Lin ;
Lin, Ho-Pan ;
Chen, Chiing-Chang .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (05) :2688-2697
[5]   Enhanced visible light photocatalytic performance of a novel heterostructured Bi4O5Br2/Bi24O31Br10/Bi2SiO5 photocatalyst [J].
Liu, Di ;
Yao, Wenqing ;
Wang, Jun ;
Liu, Yanfang ;
Zhang, Mo ;
Zhu, Yongfa .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 172 :100-107
[6]   Photocatalytic Conversion of CO2 into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects [J].
Tu, Wenguang ;
Zhou, Yong ;
Zou, Zhigang .
ADVANCED MATERIALS, 2014, 26 (27) :4607-4626
[7]   Facile microwave synthesis of novel hierarchical Bi24O31Br10 nanoflakes with excellent visible light photocatalytic performance for the degradation of tetracycline hydrochloride [J].
Xiao, Xin ;
Hu, Ruiping ;
Liu, Chao ;
Xing, Chunlan ;
Zuo, Xiaoxi ;
Nan, Junmin ;
Wang, Lishi .
CHEMICAL ENGINEERING JOURNAL, 2013, 225 :790-797
[8]   Oxygen-rich bismuth oxyhalides: generalized one-pot synthesis, band structures and visible-light photocatalytic properties [J].
Xiao, Xin ;
Liu, Chao ;
Hu, Ruiping ;
Zuo, Xiaoxi ;
Nan, Junmin ;
Li, Laisheng ;
Wang, Lishi .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (43) :22840-22843
[9]   A facile and efficient solvothermal fabrication of three-dimensionally hierarchical BiOBr microspheres with exceptional photocatalytic activity [J].
Xue, Chao ;
Xia, Jiale ;
Wang, Ting ;
Zhao, Shishun ;
Yang, Guidong ;
Yang, Bolun ;
Dai, Yanzhu ;
Yang, Guang .
MATERIALS LETTERS, 2014, 133 :274-277
[10]   Theoretical and experimental investigation of all-optical switching based on cascaded LPFGs separated by an erbium-doped fiber [J].
Zang, Zhi-Gang ;
Yang, Wen-xuan .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (10)