The use of a new ionic phosphite ligand in the hydroformylation catalyzed by rhodium complexes: Effect of reaction media

被引：3

作者：

Lyubimov, S. E. ^{[1
]}

Rastorguev, E. A. ^{[1
]}

Davankov, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2014年 / 8卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

ionic phosphite; hydroformylation; supercritical carbon dioxide; ionic liquids; rhodium; SUPERCRITICAL CARBON-DIOXIDE; HOMOGENEOUS CATALYSIS; ALKENES; HYDROGENATION; ALDEHYDES; LIQUIDS;

D O I：

10.1134/S1990793114070094

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A new method for the preparation of ionic phosphite ligands is developed. A first example of the use of this type of ligands in the hydroformylation catalyzed by rhodium complexes and conducted in organic solvents, an ionic liquid (IL), and supercritical carbon dioxide (SC-CO2) is described. It is shown that conducting the reaction in ionic liquid/supercritical carbon dioxide biphasic system may aid in increasing its rate.

引用

页码：953 / 957

页数：5

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